Final Notes 13 Flashcards

1
Q

Reversible topic 13 reactions

A

Haber process
NaOH Cl2 - NaCl NaOCl H2O
Steam methan reforming
Syngas

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2
Q

Haber condition

A

45c
200atm
Finely divided iron

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3
Q

Steam methane reforming condition

A

700-1000c
10atm
NiO s

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4
Q

Syngas to methanol condition

A

250c
50 - 100 atm
Cu

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5
Q

HI with H2O2

A

H2O2 + 2I- + 2H+ -> I2 + 2H2O

    Colourless        brown
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6
Q

Thiosulphate with iodine from

H2O2+KI or OCl- + KI

A

2 S2O3 2- + I2 -> S4O6 2- + 2I- + starch

          Brown            blue black
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7
Q

Activation energy

A

Minimum energy posessed by colliding reactant in order for a reaction to occur

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8
Q

Atom economy vs yield

A

Atom e. Based on 100% completion

Yield - extent of reaction

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9
Q

Water gas shift reaction

A

Reversible

CO2 + H2 - CO + H2O

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10
Q

Toxic substances

A

NH3
Cl2
CH3OH plus flammable

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11
Q

Hypochlorite with KI and H2SO4

A

OCl- + 2I- +H+ -> I2 + H2O + Cl-

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