Final Notes 13 Flashcards
Reversible topic 13 reactions
Haber process
NaOH Cl2 - NaCl NaOCl H2O
Steam methan reforming
Syngas
Haber condition
45c
200atm
Finely divided iron
Steam methane reforming condition
700-1000c
10atm
NiO s
Syngas to methanol condition
250c
50 - 100 atm
Cu
HI with H2O2
H2O2 + 2I- + 2H+ -> I2 + 2H2O
Colourless brown
Thiosulphate with iodine from
H2O2+KI or OCl- + KI
2 S2O3 2- + I2 -> S4O6 2- + 2I- + starch
Brown blue black
Activation energy
Minimum energy posessed by colliding reactant in order for a reaction to occur
Atom economy vs yield
Atom e. Based on 100% completion
Yield - extent of reaction
Water gas shift reaction
Reversible
CO2 + H2 - CO + H2O
Toxic substances
NH3
Cl2
CH3OH plus flammable
Hypochlorite with KI and H2SO4
OCl- + 2I- +H+ -> I2 + H2O + Cl-