Final Exam Prep Flashcards
NFPA 1500 (344/358)
Standard on Fire Department Occupational Safety and Health Program
LC50 (109)
- Concentration of an inhaled substance that results in the death of 50 percent of the test population.
- expressed in ppm, mg/liter or mg/m3 (the lower the value the more toxic the substance)
LD50 (109)
- concentration of an ingested substance that results in the death of 50 percent of the test population
- oral or dermal exposure
- expressed in mg/kg (the lower the value the more toxic the substance)
broken down in 17 paragraphs and addresses subjects such as medical monitoring and health and safety plans (17)
HAZWOPER OSHA 29CFR1910.120
The united states federal agency responsible for conducting research and making recommendations for the prevention of work related injury and illness. (379)
NIOSH (National Occupational Institutes for Occupational safety and Health
The purpose of this section is to ensure that the hazards of all chemicals produced or imported are classified and that information concerning the classified hazards is transmitted to employers and employees. (17)
OSHA
Standard for professional competence of responders to haz mat/WMD incidents (17)
NFPA 472
Standard for haz mat/WMD emergency response personnel professional qualifications (17)
NFPA 1072
LEPC (233)
- Local Emergency Planning Committee
- another potential source of information for chemical documentation for facilities
primarily assigned for use at transportation incidents involving hazardous materials (226)
Emergency Response Guidebook
detailed information bulletin prepared by a chemical manufacturer or importer that provides specific information about the product (38/231)
Safety Data Sheets
system of software applications that helps emergency responders develop safety response plans (234)
Cameo
Cameo’s atmospheric dispersion modeling program used for evaluation the release of hazardous chemical vapors (234)
Aloha
electronic resource that may be downloaded free of charge that brings a wide range of information to the hazmat responder (236)
Wiser
Supplies 24 hour a day information for incidents involving hazardous materials (142)
Chemtrec
electronic device that indicates the presence and explosive levels of combustible gases (172)
CGI Combustible Gas Indicator
the time it takes for the meter to process the material it is looking for an relaying that information to a display, light or audible notification (handouts)
response time of meters
manufacturer provided number that can be used to convert a specific device’s readout to be applicable to another function (169)
Conversion or Correction Factors
calibration and bumping meters (139)
calibration=set of operations used to standardize or adjust the values of qualities indicated by ensuring instruments
bump=verifies the instruments calibration by exposing it to a known concentration of test gas
Viscosity (37)
the measure of the internal friction of a liquid at a given temperature.
-determines the ease at which product will flow
Odor threshold (37)
odor detection threshold is the lowest concentration of a certain odor compound that is perceivable by the human sense of smell
Flash Point (38)
lowest temperature at which a liquid can form an ignitable mixture in air near the surface of the liquid and will not support continuous burning
the measurement of the ability of a material to evaporate or change from a liquid to a vapor or gaseous state (40,41,45,480)
vapor pressure
ph scale (179)
- water has a ph of 7 (neutral) at center of scale
- 7 –>0 increasing acid (red)
- 7–>14 increasing base (blue)
the pressure necessary to liquify a gas at its critical temperature (44)
critical pressure
ability of a substance to vaporize easily at a relatively low temperature (38,580)
volatility
polymerization(74,75,576)
chemical reactions in which two or more molecules chemically combine to form larger molecules
-reaction can be violent
chemical reaction between two or more materials that changes the materials and produces heat (72,569,570)
Exothermic
chemical reaction in which a substance absorbs heat energy (72,569,570)
endothermic
substance that modifies (usually increases) the rate of a chemical reaction without being consumed in the process (74,567)
catalyst
Concentration (77)
- % (mass or volume) of a material dissolved in water or other solvent.
- quantity of a chemical material inhaled for purposes of measuring toxicity
- quantity of a material in relation to a larger volume of gas or liquid
2 or more liquids capability to mix together (79,574)
miscibility
property of some molecules to have discrete areas with negative and positive charges (41,49,576)
polarity
degree to which a solid, liquid or gas dissolves in a solvent (usually water) (78,578)
solubility
degree to which a solid, liquid or gas dissolves in a solvent (usually water) (78,578)
solubility
specific gravity
- substance less than 1 floats on water
- substance greater than 1 sinks in water
NFPA -Class 1 (Level A) suit is required for NFPA rating of _____ or higher
3
non-pressure tanks (309,573,576)
contents under low pressure (.5 psi)
pressure tanks (309,573,576)
contnets under pressure (.5 psi +)
-May be underground (pressure above 15 psi)
5 types of packaging for radiation containers for transport (strict regulations) (315)
1) excepted
2) Industrial
3) Type A
4) Type B
5) Type C
pipelines (306)
- =primarily carry liquid petroleum products, natural and manufactured gas.
- buried 30-36 inches below ground
- caution, warning and danger markers
similar to jerry cans; limited use, non bulk container used almost exclusively for hazardous materials. Plastic, glass, or steel. Narrow neck contain 6-16 gallons (251)
Carboys
not classified by DOT, individual steel tubes, gas under pressure (279)
Tube trailers
signs of damaged cargo tank. weak points must be stabilized or offloaded. damaged welds are critical if the crack extends to the container itself (490)
Scores/Cracks/Dents
patching types (499)
breach in container too large to be plugged. slow the leak to develop a plan (e.g. box patch, hook bolts, pipe patches)
chlorine kits (499)
- A-kit: compressed gas cylinders (100-150 lbs)
- B-Kit: ton containers
reduces the risk of static electricity to an operation (506,537)
grounding and Bonding
come inner ring, may have bung leaks, chime leaks, sidewall punctures, overpacking is an option(513)
Drums
Damaged drum placed inside another container (514)
Overpacking
sliding a drum on its side into an overpack drum (515)
Slide-In method
rapid chilling of a liquified compressed gas as it transitions from a liquid state to a vapor state (41,508)
auto-refrigeration
concise report that details and analyzes incident operations, lessons learned and recommendations (554)
After Action Report
fixed tanks and facilities (309-311)
identifying the type of hazardous material present can be difficult (preplanned)
DOT Bulk Packaging (notes)
- 119 gallons+ (liquid)
- 800 pounds + (solid)
- water capacity greater than 1000 lbs (gas)
DOT Bulk Packaging (notes)
- 119 gallons+ (liquid)
- 800 pounds + (solid)
- water capacity greater than 1000 lbs (gas)
established set of chemical protective PPE ensembles (390)
EPA
CPC maintenance, testing, and record keeping
OSHA
requirements for a minimum level of protection for responses personnel facing exposure to specified chemicals (398)
NFPA 1991
process in which a chemical passes through a protective material on a molecular level (391)
Permeation
process hazardous materials enters an opening or puncture in a protective material (391)
penetration
strength, toughness and ability to resist (391)
Resistance
material is altered through contact, use or wear (391)
degradation
donning and doffing (424,430)
performed in the cold zone, can be time consuming (2 assistants per 1 responder), must be done with care
penetration of one substance into the structure of another, such as the process of picking up a liquid containment with an absorbent. can be wiped off (442,565)
absorption