Final Exam- C3 Flashcards
*“Atomos” concept (5th century
*
*“Matter is composed of tiny
indivisible objects”
*
Not accepted by Aristotle and was
later ignored for centuries
Democritus
Atomic theory
John Dalton
*
Pioneered investigations on
Cathode Rays
Julius
Plucker
*
Discovered the Electron (1897)
*
Plum Pudding Model of the Atom
*
Charge to mass ratio of electron =
1.758820 x 10 11 C/kg
Joseph J. Thomson
*
Oil drop Experiment
*
Charge of Electron = 1.602 x 10 19 C
Robert Millikan
*
α particle scattering experiment
*
Discovered the Proton
*
Nuclear Model of the Atom (1904)
Ernest Rutherford
*
Originator of the quantum
theory (1900)
*
Blackbody radiation
*
*quanta
*
E = hv
Max Planck
*
Photoelectric Effect (1905)
*
*“photon
Albert Einstein
Planetary Model of the Atom (1913)
Niels Bohr
*
Wave particle duality (1923)
physical entities possessing
both wave like and particle like
characteristics.
Louis de Broglie
*
Quantum mechanical model (1926)
*
Ĥ ψ = E ψ
Erwin
Schr ödinger
*
Uncertainty Principle (1927)
*
Matrix Mechanics (1925)
Werner Heisenberg
*
Discovered the neutron (1932)
James Chadwick
main energy levels
distance of e from nucleus
values: 1, 2, 3 …
Principal Quantum Number
shape of the orbital
values: 0 to (n 1)
Azimuthal/ Angular Quantum number
orientation of orbital in space
values: l to +l, including 0
Magnetic Quantum Number
how two (2) e in the same orbital will interact
maximum of 2 e per orbital (with same n, l and m l
values: +½ (up spin) and ½ (down spin)
Spin quantum number
no 2 e can have the same set of
quantum numbers
Pauli’s Exclusion Principle
every orbital in a subshell is singly occupied
with 1 e before any one orbital is doubly occupied, and all e
in singly occupied orbitals have the same spin
Hund’s Rule
energy increases with increasing ( n+l )
value; for same values of ( n+l ), energy increases with
increasing n
Madelung’s Rule
the distribution of electrons of an atom or
molecule (or other physical structure) in
atomic or molecular orbitals
Electron Configuration
nuclear charge felt by an electron from both the actual
nuclear charge Z ), which is equal to the number of
protons and the repulsive effects of the other electrons
(shielding, S equal to the number of core electrons).
Effective Nuclear Charge (Z
eff
Zeff formula
Zeff= Z-S
energy required to remove e
Ionization Energy
energy evolved when an atom accepts e
or energy required
to detach one electron from a negatively charged ion of an
atom.
Electron Affinity
ability of bonded atoms to attract shared e
Electronegativity
mixing of two or more atomic orbitals
to form a new set of hybrid orbitals.
Hybridization
bonds are formed by sharing
of e from overlapping atomic orbitals.
Valence bond theory
formed by sharing of electrons
covalent bond
ability of an atom to attract shared
pair of electrons
electronegativity
unequal sharing of
electrons greater electron density around
one of the two atoms
polar covalent
equal sharing of
electrons
polar covalent bonds