Final: All structures (Ben/Lukas) Flashcards
tyr
neutral, polar
aromatic
- side chain is phenol

Propionic Acid

Testosterone

Creatinine
(breakdown product of creatine-P)

acetoacetic acid
(basically just two acetic acids combined)

epinephrine
(decarboxylated, double hydroxlated and methylated tyrosine)

tryptamine
(decarboxylated tryptophan)
val
neutral, nonpolar
- one of the 3 branched-chain AAs
arg
basic, polar
- pka of side chain is more basic than amine
- side chain is guanidine after three CH2s

xanthine
(purine with 2 oxo grps)

Cortisol

asn
neutral, polar
the amine in the side chain is NEVER protonated
- contains carboxamide (carboxyl w/ NH2 replacing OH) attached to CH2
glu
acidic, polar
- side chain is carboxyl after two CH2s
adenine
(purine with only an amino grp)

Cholesterol

Cholic Acid
(dont confuse with cholesterol … has more -OH grps on its rings plus has -COOH on side chain rather than that branching of cholesterol)

gamma carboxy glutamate

citrate

GABA
- decarboxylated glutamate
ile
neutral, nonpolar
2 chiral centers (4 configurations)

fumarate

cGMP
(note the cyclized P and ribose, plus the =O and -NH2 on the purine means guanine)

acetone

Acetylcholine
(triple methylated N of choline plus acetyl grp)
leu
neutral, nonpolar
- one of the 3 brainched chain AAs
glycocholic acid
(dont confuse with cholesterol or cholic acid… that long side chain has a nitrogen from the glycine which is conjugated to cholic acid)

fructose-1, 6-bisphosphate

isocitric acid

fructose-6- phosphate
lys
basic, polar
- pka of side chain is more basic than amine
- side chain is an amino group after four CH2s
Glycine

ethanolamine
(ethanol with an amine… ya big idiot)

aldosterone

ribose-5-phosphate

Histamine
(decarbed His)
phe
neutral, nonpolar
aromatic
thr
neutral, polar
2 chiral centers
phosphatidylcholine
- choline is the z group
- found in outer layer of lipid bilayer + in pulmonary surfactant, abundunant in brain + nerves
- AKA lecithin

Ornithine
(dont confuse with Lys! … Lys has one more -CH2- in its R group)
cytosine
(pyrimidine with amino and oxo)

Progesterone

Sec (Selenocysteine)
Neutral
Polar
- selenium replaces sulfur in cysteine’s thiol group
Sphingosine
- found in various sphingolipids in cell membranes
- important in signaling as well
(looks like a glycerol with middle OH subbed by amino and 3rd H subbed by 15-C w/ double bond on first C)
alanine

carnitine

alpha-amino-beta-ketoadipate
(starting from the right side… there is an alpha amino group and beta ketone… this is the intermediate of ALA synthase in delta-aminolevulinate synthesis)

glycerol

diacylglycerol
glycerol backbone plus 2 FAs (R grps) connected via ester linkages

glucose
Phosphatidic Acid

Beta Alanine
(alanine with amino in beta position)

α- ketoglutarate

cAMP
(note the cyclized phosphate and ribose and the single amino grp on the purine = adenine)

Cephalin
AKA phosphatidylethanolamine
(the longer name makes more sense… is a phosphatidic acid with ethanolamine attached at the P grp … R grps are fatty acids)

glucosamine

2-phosphoglycerate

oxaloacetate OXA

dihydroxyacetone phosphate DHAP
ignore Mg2+

malate

Urea

fructose

glucuronic acid
(NOT glucose! because it has a -COOH instead of -CH2OH)

carbamoyl phosphate
(ammonia + bicarbonate + phosphate … sort of)

glycerinaldehyde-3-phosphate

Uric Acid
(purine with 3 oxo groups)

serotonin
(decarboxylated and hydroxylated Trp)

delta-aminolevulinic acid
(decarboxylation of the alpha-amino-beta-ketoadipate intermediate in the ALA synthase rxn)

acetic acid

Estradiol

galactose

norepinephrine
(decarboxylated and double hydroxylated tyrosine)

B-hydroxy-B-methyl-glutarate
(AKA HMG as in HMG-CoA)
(the B OH and B -CH3 right in the middle of the molecule give it away)

glucose-6-phosphate (alpha D)

Creatine
(made from Gly and Arg … into guanidinoacetate … then methylated on that middle N)

1,3-BPG

glucose-1-phosphate

phosphoenolpyruvate PEP
asp
acidic, polar
- side chain is carboxyl after one CH2
met
neutral, nonpolar
- S comes after two CH2s

6-phosphogluconate

3-phosphoglycerate

Hydroxyproline
hypoxanthine
(purine with only one oxo grp)
thymine
(pyrimidine with 2 oxo and 1 methyl grp… ie methylated uracil)
ser
neutral, polar

Citrulline
(don’t mistake for arginine!)

gln
neutral, polar
- contains carboxamide (carboxyl w/ NH2 replacing OH) attached to second CH2

taurocholic acid
(dont confuse with… cholesterol OR cholic acid OR glycocholic acid…. there’s an S in there, ya big dummy)
pro
neutral, nonpolar
not an amino acid, but a cyclic amino or imino acid
with a secondary amide contained within the ring

Androstenedione
uracil
(pyrimidine with 2 oxo grps)

creatine phosphate
his
basic, polar
aromatic
- side chain is imidazole attached to one CH2 via the C furthest from the lone N

beta-hydroxy-butyrate
(OH on the beta carbon)
trp
neutral, polar
aromatic
- contains an indole (benzene + pyrrole) group attached to -CH2 via the double bonded C of its pyrrole furthest from the N

succinate
cys
neutral, polar
- contains a thiol (R-S-H) on a CH2
guanine
(purine with amino and oxo grp)
Know how to identify nucleotide AND deoxynucleotide mono, di and triphosphates…
basically just see if the ribose is 2-deoxy or not … then check what base it is… then see how many Ps