F325 - Rates, Equilibrium and pH Flashcards

0
Q

Describe zero order.

A

The rate is unaffected by changing the concentration in A.

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1
Q

What is the rate of reaction?

A

The change in concentration of a reactant or product per unit time.

Change in conc/time

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2
Q

Describe first order.

A

Proportional to the increase in concentration.

Eg increase of 3 then increase of 3.

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3
Q

Describe second order.

A

Increases proportional to the square of the concentration.
Eg concentration increases by 3.
Rate increases by 9.

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4
Q

What does a half life graph look like for first order?

A

Constant half life.

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5
Q

Describe a zero order Half life graph.

A

Half life decreased with time at a constant rate.

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6
Q

Describe a second order half life graph.

A

1/x

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7
Q

What changes Kc?

A

Temperature

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8
Q

What does a Kc value of 1 indicate?

A

Equilibrium is halfway between reactants and product

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9
Q

What does a Kc above 1 suggest.

A

Product favoured, shifts to the right.

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10
Q

When the forward reaction is endothermic how does Kc increase?

A

As temperature increases so does Kc.

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11
Q

What is Kc?

A

Products/reactions

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12
Q

Why is a Brønsted-Lowry acid and base?

A

Acid: any substance for which a proton can be removed.

Base: any substance that can remove a proton from an acid.

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13
Q

What is an alkali?

A

A base that dissolved in water forming OH- ions.

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14
Q

What is an acid base conjugate pair?

A

A pair of two species that transform into each other by gain or loss of a proton.

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15
Q

What is pH?

A

-log[H+]

16
Q

What I [H+]?

A

10^-pH

17
Q

What is a strong and weak acid?

A

Strong completely dissociates in water.

Weak partially dissociates in water.

18
Q

In a strong acid what does H+ equal?

A

[H+]=[HA]

19
Q

What does [H+] equal in weak acids?

A

[H+]=[A-]

20
Q

Describe Kw in water, acidic and alkaline solutions.

A

Water H+=OH-

Acid H+>OH-

Alkaline H+<OH-

21
Q

What is Kw?

A

[H+][OH-] both (aq)

1 x 10^-14

22
Q

What is a buffer solution?

A

A mixture that minimises pH changes on addition of small amounts of acid or base.

23
Q

How is a buffer solution made?

A

A mixture of a weak acid and it’s conjugate base.

24
Q

Describe the action of a buffer solution HA.

A

HA ~ H+ + A-

When H+ is added A- reacts and eq shift to the left removing the H+ ions.

When OH- is added H+ react and eq shifts to the right.

25
Q

What is equivalence point?

A

The point in a titration at which the volume of one solution has reached exactly the volume of the second solution.