F324 Past Papers Flashcards

0
Q

What happens wen something reacts with tollens?

A

It is oxidised.

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1
Q

When bromine reacts with phenol what would you observe to happen?

A

A white precipitate forms, And bromine decolourise.

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2
Q

What are problems with kukele?

A

Enthalpy change of hydrogenation is less exothermic than expected.

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3
Q

What is retention time?

A

The time from the injection of a sample for the component to leave the column.

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4
Q

What are problems with chiral drugs?

A

Production or separation of a single isomer can be difficult.
Another isomer may be harmful.

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5
Q

How can problems with chiral drugs be overcome?

A

Enzymes.

Chiral synthesis.

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6
Q

How can you derive the structure of a compound through the Bradys test?

A

Take the melting point of product and compare with known values.

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7
Q

When do you leave the ends?

A

When asked for repeats.

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8
Q

How does a liquid stationary phase separate compounds in a mixture?

A

Relative solubility

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9
Q

What are problems with kukele?

A

Enthalpy change of hydrogenation is less exothermic than expected.

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10
Q

What is retention time?

A

The time from the injection of a sample for the component to leave the column.

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11
Q

What are problems with chiral drugs?

A

Production or separation of a single isomer can be difficult.
Another isomer may be harmful.

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12
Q

How can problems with chiral drugs be overcome?

A

Enzymes.

Chiral synthesis.

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13
Q

How can you derive the structure of a compound through the Bradys test?

A

Take the melting point of product and compare with known values.

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14
Q

When do you leave the ends?

A

When asked for repeats.

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15
Q

How does a liquid stationary phase separate compounds in a mixture?

A

Relative solubility

16
Q

Why does the nitration of benzene make numerous products?

A

Substitution of NO2 at different points of the ring.

17
Q

Write the formula of the salts formed when C2H5NH2 reacts with:
Sulphuric acid
Ethanoic acid

A

(C2H5NH3+)2 SO42–

C2H5NH3+ CH3COO–

18
Q

What is condensation polymerisation?

A

Monomers joining to form a chain and another small molecule like H2O.

19
Q

What increases water solubility?

A

Forming more H bonds

20
Q

What is the observation made when something is oxidised by K2Cr207?

A

Turns green or blue

21
Q

What does the D2O shake show?

A

It removes an OH or NH peak

22
Q

Explain the relative resistance to bromination of benzene and an alkene.

A

Benzene has delocalised pi bonds.
Alkene has localised pi bonds between 2 carbons.
Benzene has a lower e density.
Benzene polarises Br2 less.