Extracting Metals and Equilibria Flashcards

1
Q

What is a reversible reaction

A

Where the products can react with each other to produce the original reactants

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2
Q

What is the Haber Process

A

An industrial process used to form ammonia from hydrogen and nitrogen

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3
Q

Where is the nitrogen in the haber process obtained from

A

The air - it is 78% nitrogen

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4
Q

Where is the hydrogen in the haber process obtained from

A

Hydrocarbons

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5
Q

What are examples of hydrocarbons

A
  • Natural gas
  • Crude oil
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6
Q

What temperature is the haber process carried out at

A

450 °C

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7
Q

What pressure is the haber process carried out at

A

200 atmospheres

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8
Q

What is the catalyst used in the haber process

A

Iron/Fe

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9
Q

What happens to the reactants when they react

A

Their concentrations decrease

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10
Q

What happens to the products when they are made

A

The reactants concentration increase

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11
Q

What happens when the concentrations decrease

A

The forward reaction will slow down

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12
Q

What happens when the concentrations increase

A

The backward reactions will speed up

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13
Q

What happens after a while of the reversible reaction

A

The forwards and backward reactions will be going at the same rate

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14
Q

What is it called when both reactions happen at the same rate

A

Equilibrium

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15
Q

What happens at equilibrium

A

Both reactions are still happening, but there is no overall effect

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16
Q

What happens at dynamic equilibrium

A
  • The forward and backward reactions are happening at the same time and the same rate
  • The concentrations of the reactants and products have balanced and won’t change
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17
Q

How can equilibrium be reached

A

If the reversible reaction happens in a closed system

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18
Q

What is a closed system

A

No reactants or products can escape

19
Q

What 3 things affect the position of equilibrium

A
  • Temperature
  • Pressure
  • Concentration
20
Q

What are fertilisers used for

A

To replace the mineral ions needed by plants - promotes plant growth

21
Q

What are important elements in fertilisers

A
  • Nitrogen (N)
  • Phosphorus (P)
  • Potassium (K)
22
Q

What is Ammonium Nitrate an example of

A

A Nitrogen-rich fertiliser

23
Q

What is ammonium nitrate

A

A salt manufactured by reacting ammonia solution with dilute nitric acid

24
Q

How is ammonium nitrate manufactured

A

The Haber Process

25
What is Nitric Acid manufactured by
Ammonia in stages
26
What is Ammonium Sulfate an example of
A nitrogenous fertiliser
27
How if Ammonium Sulfate made
In a lab by reacting ammonia solution with dilute sulfuric acid
28
How is ammonia solution and dilute sulfuric acid obtained for lab prep
They are bought from chemical manufacturers
29
What type of process is buying the substances
A batch process
30
What is a batch process
A small amount is made, the apparatus is cleaned, and then another small amount is made
31
Whats the downside to a batch process
It's difficult to automate
32
How are substances made for industrial production
They are made from their raw materials
33
What type of process is industrial production
A continous process
34
What is a continous process
When the reactants are constantly fed into the reactors and products are removed
35
When is a conitnous process stopped
Only rarely to maintain and clean the equipment
36
What happens during dynamic equilibrium
- The forward and backward reactions still happen, and at the same rate - The concentrations of all reacting substances do not change
37
What factors affect the position of dynamic equilibrium
- Temperature increased - Pressure increased (in a reaction involving gases) - Concentration (of a reacting substance) increased - Catalyst added
38
How does a temperature increase affect the position of dynamic equilibrium
It moves the equilibrium in the direction of the endothermic reaction
39
How does a pressure increase affect the position of dynamic equilibrium
The equilibrium moves to the side of the balanced equation with the fewer molecules
40
How does a concentration increase affect the position of dynamic equilibrium
The equilibrium moves away from the reacting substance in the balanced equation
41
How does a catalyst being added affect the position of dynamic equilibrium
There is no change
42
How do chemical manufacturers make a profit
They choose reaction confitions that produce an acceptable product yield in an acceptable time
43
What isn't allowed to happen to reactions to make a profit
- They aren't allowed to reach equilibrium - it isn't profitable if it takes years - They shouldn't choose conditions that are too expensive
44