Experiment C: Compounds Of Copper Flashcards
What does the reaction with copper and nitric acid form?
Water soluble copper(II) nitrate
Copper does not react readily with sulfuric or hydrochloric acids, what does it react with?
Nitric acid (HNO3) It is a strong oxidizing agent
Which oxidation state of copper is more stable?
The +2 oxidation state (rather than the +1)
Describe the traditional copper cycle
Cu->Cu(NO3)2->CuCO3->CuSO4
What are the products of the reaction between nitric acid and copper metal?
Copper (II) nitrate
Nitrogen monoxide/ nitric oxide (NO) -colourless gas
Water
What happens to Nitrogen monoxide when it reacts with oxygen
The colourless NO reacts immediately with oxygen to form the poisonous reddish brown NO2 (nitrogen dioxide)
How do we modify the traditional copper cycle experiment?
We begin with Cu(NO3)2x2.5H2O(s) to prepare aqueous Cu(NO3)2. We add sodium carbonate (Na2CO3) to cause a CuCO3 precipitate. It is then reacted with sulfuric acid to form CuSO4
Is copper carbonate soluble?
No it precipitates in aqueous solution
In water NH3(aq) acts as a
Weak base
Small amounts of aqueous ammonia added to copper (II) sulfate leads to the formation of ____. Large amounts leads to ____.
1) light blue Cu(OH)2(s)
2) dark blue complex ion Cu(NH3)4+2(aq)
Copper can be recovered through the following reaction:
The oxidation-reduction reaction between zinc and copper
Zn(s)+Cu+2–>Zn+2 + Cu(s)