Exam 4 Flashcards

1
Q

principal quantum number

A

has to deal with size, n and total nodes is n-1

n=1 to infinity

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2
Q

angular momentum or azimuthal

A

has to do with shape, energy in multi electron atoms.

l=0 to n-1
planar nodes = l

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3
Q

magnetic

A

orientation

ml goes to -l to + l

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4
Q

n is

A

principal quantum number

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5
Q

l

A

angular momentum or azimuthal

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6
Q

ml is

A

magnetic number

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7
Q

ms is

A

spin

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8
Q

when l is 0

A

orbital is s

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9
Q

l is 1

A

p orbital

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10
Q

l is 2

A

d orbital

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11
Q

how many angular/planar nodes

A

l

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12
Q

how many radial nodes

A

n-l-1

but just n-1 if its in principal quantum num

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13
Q

D =

A

is supposed to be delta symbol - See lecture notes for clarification

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14
Q

photon energy is

A

h times frequency

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15
Q

c is

A

frequency lamda

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16
Q

momentum is

A

h/λ

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17
Q

kin energy is

A

KE = ½ mv2

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18
Q

total energy using systems is

A

E = KEsys + PEsys

19
Q

Q IS

20
Q

delta e is

A

∆E = q + w

heat and work

21
Q

∆E and heat

A

heat and volume

= qV

22
Q

delta h with delta e

A

∆H = ∆E + P ∆V

pressure

23
Q

∆H= qp

A

heat and pressure

24
Q

delta h rxn

A

∆H°rxn = ∆H° products − ∆H° reactants

25
delta h rxn
∆Erxn = BEreactants − BEproducts
26
state functions
energy, enthalpy, temp, vol and press
27
path functions
heat and work
28
enthalpy of formation is
products - reactants
29
bond e
reactants- products
30
same charge, small distance
has high repulsion and high el
31
same charge, greater separation
less repulsion and lower el
32
different charge, small separation
greater attraction and lower el
33
different change, large separation
less attraction and higher el
34
draw the electrostatic potential curve
ha
35
gases move at
different speeds, even same species
36
pressure volume work
NEGATIVE pdelta v = w
37
as you decrease the distance between two particles, what happens to the absolute value of the magnitude of the el?
it increases
38
nodes vs density
nodes have low amplitude and low density
39
radial probability distribution curve peaks
show the n number
40
radial probability distribution curve dips
show the nodes
41
Photoelectric effect
when you hit a material with radiation, electrons will come off it
42
bond energy is
always positive
43
go look at the lecture questions
HA