Exam 4 Flashcards

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1
Q

n (principle quantum number)

A

the distance of the electron from the nucleus
n=1,2,3…

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2
Q

l (angular quantum number)

A

Value relates to the shape of the orbital
l = n-1 (0, 1, 2…

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3
Q

ml (magnetic quantum number)

A

Value relate to how orbital is oriented in space i.e. which way orbital is pointing
range from -l to +l (…-2, -1, 0, 1, 2)

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4
Q

if l is 0 ->
if l is 1 ->
if l is 2 ->

A

s orbital
p orbital
d orbital

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5
Q

What works about bohr’s model

A
  • The model also works fairly well for hydrogen like atoms such as lithium and helium
  • the model does explain discrete emission atomic spectrum
  • electron existing energy levels with the lowest being n=1
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6
Q

failures of bohr’s model

A

Because Boris model of the Adam treat electrons as particles and not particles and waves his model ultimately fails because
* model only works perfectly for hydrogen
* model contradicts Heisenberg uncertainty principle
* the model never explained why electrons are in orbit

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7
Q

m sub s (electron spin)

A

+1/2 or -1/2 (just assign one of the two directions to each electron)

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8
Q

Penetration and shielding

A

how strongly electrons/orbitals feel the nucleus’ pull

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9
Q

Penetration

A

core electrons feel the nucleus more
- core e-s (1s, 2s) penetrate through to the nucleus

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10
Q

Shielding

A

outer electrons (valence) are shielded from the nucleus by core electrons because electrons don’t attract

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11
Q

atomic radius increases

A

→ and ↓

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12
Q

ionization energy increases

A

↑ and →

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13
Q

electronegativity increases

A

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14
Q

non metallic character increases

A

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15
Q

metallic characters

A

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16
Q

electron affinity

A

how much an atom wants to gain an electron

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