Exam 4 Flashcards
n (principle quantum number)
the distance of the electron from the nucleus
n=1,2,3…
l (angular quantum number)
Value relates to the shape of the orbital
l = n-1 (0, 1, 2…
ml (magnetic quantum number)
Value relate to how orbital is oriented in space i.e. which way orbital is pointing
range from -l to +l (…-2, -1, 0, 1, 2)
if l is 0 ->
if l is 1 ->
if l is 2 ->
s orbital
p orbital
d orbital
What works about bohr’s model
- The model also works fairly well for hydrogen like atoms such as lithium and helium
- the model does explain discrete emission atomic spectrum
- electron existing energy levels with the lowest being n=1
failures of bohr’s model
Because Boris model of the Adam treat electrons as particles and not particles and waves his model ultimately fails because
* model only works perfectly for hydrogen
* model contradicts Heisenberg uncertainty principle
* the model never explained why electrons are in orbit
m sub s (electron spin)
+1/2 or -1/2 (just assign one of the two directions to each electron)
Penetration and shielding
how strongly electrons/orbitals feel the nucleus’ pull
Penetration
core electrons feel the nucleus more
- core e-s (1s, 2s) penetrate through to the nucleus
Shielding
outer electrons (valence) are shielded from the nucleus by core electrons because electrons don’t attract
atomic radius increases
→ and ↓
ionization energy increases
↑ and →
electronegativity increases
↗
non metallic character increases
↗
metallic characters
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