Exam 3 Flashcards
What is a reduction reaction?
A chemical reaction where a reactant gains an electron, & often a hydrogen, too. It is the opposite of oxidation. These 2 are often paired in a redox reaction
What does thermodynamics study?
Energy changes
What does the first law of thermodynamics state?
Energy cannot be created or destroyed
What does the second law of thermodynamics state?
Energy transformations are not 100% efficient. Some energy will be lost as heat in every transformation. In other words, entropy is continuously increasing
What is free energy?
The energy available to do work. For our purposes, free energy usually refers to the energy contained within the bonds of a molecule
What does endergonic mean?
It means that the products of a reaction contain more energy than the reactants, so additional energy from other sources is required. Positive ∆G. These reaction cannot happen spontaneously.
What does exergonic mean?
It means that the products of a reaction contain less energy than the reactants, so energy is released. Negative ∆G. These reactions may occur spontaneously.
What is energy?
The ability to do work
What does a negative ∆G mean?
Energy is released
Why is ATP good for storing energy?
The bond between the phosphates is unstable & easy to break. This reaction releases a lot of energy.
What is a substrate?
A reactant molecule that an enzyme is acting upon
What is the active site of an enzyme?
It’s where the reactant or substrate goes so that the enzyme can catalyze the reaction
What is an inhibitor?
A substance that binds to an enzyme to prevent it binding to a substrate & working.
What is a allosteric inhibitor?
An inhibitor that binds to a part of the enzyme opposite the active site (the allosteric site) & causes the shape of the active site to change so that the substrate can’t fit, inhibiting the enzyme from working
What does metabolism mean?
All of the chemical processes that happen in a cell
What is a biochemical pathway?
A sequence of chemical reactions catalyzed by enzymes, where each enzyme catalyzes the product of the previous enzyme’s reaction
What does an enzyme do?
Enzymes are catalysts, meaning they decrease the energy required for a chemical reaction to happen. In simple terms, they make the reaction easier & faster.
How is energy released from ATP?
A phosphate-phosphate bond is broken by hydrolysis. The energy that was contained within the bond can then be used.
What is the ATP cycle?
The process by which ATP is continuously hydrolyzed into ADP + P to provide the energy for endergonic reactions in the cell, then ADP is recombined with P to synthesize ATP again using energy from exergonic reactions, often in the mitochondria, using energy from cellular respiration.