Exam 2: Intermolecular Forces Flashcards
Intermolecular Forces
force of attraction that occurs between atoms, molecules, and ions during to their proximity in space to each other
weaker than intramolecular forces (ionic, covalent, metallic bonds)
can occur between more than one atom/molecule in the same space
How can intermolecular forces appear stronger?
They can have a large number of interactions, therefore appear to be stronger
The closer the proximity of atoms the _______ interactions
more
Place in order from least to most intermolecular forces: Gas, Solid, Liquid
Gas (furthest distance between atoms/molecules)
Liquid (closer in proximity)
Solid (most intermolecular forces, tightest in proximity and distinct arrangement to maximize the intermolecular forces)
Intermolecular forces come about because of ______
charges (partial charges develop because of an unequal sharing of electrons)
How do you denote a partial charge?
lowercase delta (+ or -)
T/F
The magnitude of a charge (real or partial) affects the strength of the attraction
True
What is a dipole?
A dipole occurs when the polarity is unequally distributed (think polar covalent bonds)
pushes from + to -
What type of bond would you see equal sharing in?
non-polar covalent
In a molecule of H2O, which ion has what partial charge and where does it push to (which way does the arrow point)?
H has a + partial charge, O has a - partial charge, the arrow points FROM H and TO O
T/F
The distance between species affects the strength of the attraction
True
If the attractive force between two particles is strong, how does this affect the resistance to moving/breaking apart?
The stronger the force of attraction, the more they resist moving/breaking apart
Define polarity
The separation of electric charge along a bond due to differences in the electronegativity of the bonded atoms
Define an electric dipole or dipole moment
Electron density that is not equally shared between two atoms leading to the formation of partial charges
When denoting the dipole moment, which way does the arrow point?
towards the more electronegative atom
How many drops can fit on a penny?
more than 100 drops
Explain surface tension and its application of intermolecular forces
- liquid’s resistance to increase its surface area
- the stronger the intermolecular forces, the more energy required to increase the surface area
- to minimize the surface area, liquids form spherical drops
If your car is freshly waxed, what happens to the water and what is this an application of?
the water will slide right off, this is an application of intermolecular forces in surface tension