Exam 2 Chapter 3 And 4 Flashcards
Oxidation state rule #1 to find the oxidation state in a neutral compound
In a neutral compound all oxidation numbers add to zero 0.
Make an equation that adds to 0
Oxidation state rule #2 to find the oxidation state in an ION….?
Hint SO4²-
In an ION the sum of oxidation numbers add to the ion charge Ex.
SO4²- the ion is a -2 so
(O)xygen is -2 X 4 = -8
(S)ulfur must be +6
Because +6 + 4(-2) = -2 which is the charge of the ion
Free elements or monatomic substances where there is only one type of atom in the substance have an oxidation number of … ?
Rule #3
Zero
Ex. Na, Fe, H2, O2, S8 all oxidation numbers are 0
What is the oxidation number of Fluorine F?
Rule #4
Has precedence over oxygen being -2
Hint like the alphabet
-1
Always beats (comes before) the “oxygen has a -2 oxidation number” rule
Ex.
In OF2
Oxygen has a +2 charge because
Fluorine has a -1 charge and the compound
Must be neutral or have a 0 net charge
+2 + 2(-1) = 0
What is the oxidation number of F2?
Hint - Rule 3
Although F is always has an oxidation number of -1
It is a free element and is made of one type of atom so it is
0
Rule #3
Rule #5 What is the oxidation number of group 1 , group 2 and group 3 metals?
Always
Group 1 = +1
Group 2 = +2
Group 3 Al and Ga = +3
UNLESS RULES 1-4 APPLY
WHICH TAKE PRECEDENCE OVER THIS RULE
RULE #6 What is the oxidation number for hydrogen with nonmetals and hydrogen with metals or boron?
H with metals = +1
H with non-metals AND Boron = -1
UNLESS rules 1-5 apply
RULE #7 What is the oxidation numbers of oxygen?
And what are the 2 EXCEPTIONS
Oxygen is always -2
Except
when bonded to Flourine
When in peroxide H2O2 or Na2O2
RULE #8 LAST RULE what are the oxidation numbers for
Group 17(7A) =
Group 16(6A) =
Group 15(5A) =
If none of the other rules apply
Group 17(7A) = -1
Group 16(6A) = -2
Group 15(5A) = -3
Is K+ + Cl- —> KCl. A Redox reaction?
If not make it a redox reaction
NO
Because there is no transfer of electrons The equation starts with ions. The ions were not made as a result of the reaction
K + Cl —> KCl
Both K and Cl are neutral and became ions during the reaction.
Name CuCl
CuCl2
And why
Copper (1) Chloride
Copper (2) Chloride
The chloride and copper one has an assumed -1 ion charge, which would make the copper a +1 ion
The chloride and copper two chloride has a two subscript, making it -2, so the copper would be the +2 ion