Equilibria Flashcards

1
Q

Hydrated copper sulphate

A

CuSO4 . 5H2O CuSO4 + 5H2O

add heat

Products are endo

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2
Q

Ammonium chloride

A

NH4Cl NH3 + HCl

heated

Products are endo

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3
Q

Dynamic equilibrium

A
  • when the rate of the forward reaction is equal to the rate of the reverse reaction (overall amount of products and reactants stay the same)
  • occur in closed conditions (no substances added or removed)
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4
Q

Changing equilibrium (or Chatelier’s principle)

A
  • increasing/decreasing the concentration of substance present, changing temperature or pressure
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5
Q

Changing concentration

A
  • Increasing concentration of reactants favours products

- decreasing concentration of reactants favours reactants

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6
Q

Changing temperature

A
  • if forward reaction is endothermic, increasing the temperature will increase the yield
  • if forward reaction is exothermic, decreasing the temperature will increase the yield
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7
Q

Changing pressure

A
  • increasing pressure favours side with least number of moles
  • decreasing pressure favours the side with the most moles
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8
Q

Catalyst on equilibrium

A
  • adding catalysts speed up both reactions so has no affect on the yield
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9
Q

What does the Haber process manufacture

A

Ammonia

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10
Q

Steps of the Haber process

A
  • hydrogen and nitrogen mixed with ammonia
  • mixture is cooled so the ammonia is liquefied
  • ammonia is removed and nitrogen and hydrogen are recirculated
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11
Q

Conditions for making ammonia

A
  • temperature 450 degrees Celsius
  • 200 atmospheres of pressure
  • iron catalyst
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12
Q

Making sulphuric acid

A
  • S+O2 —> SO2 (sulphur dioxide)
  • 2SO2 + O2 —> 2SO3 (sulphur trioxide)
  • SO3 + H2SO4 (sulphuric acid) —> H2S2O7 (oleum)
  • H2S2O7 + H2O —> 2H2SO4
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13
Q

Conditions for making sulphuric acid

A
  • 450 degrees Celsius
  • 2 atmospheres
  • vanadium oxide catalyst
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14
Q

Uses of ammonia

A

Nitric acid

Fertiliser

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15
Q

Uses of sulphuric acid

A

Detergents
Fertilisers
Paints

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