EOY exam Flashcards

1
Q

What are the colours of the metal ions flame test?

A
Lithium, Li+ -	Red
Sodium, Na+	- Yellow
Potassium, K+	 - Lilac
Calcium, Ca2+ - Orange-red
Barium, Ba2+	- Green
Copper, Cu2+	 - Blue-green
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2
Q

Why do we clean the wire loop in the flame test?

A

To sterilise it to ensure that the results are accurate

To ensure an adequate amount of powder sticks to it

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3
Q

Why do we dip the wooden stilts in hydrochloric acid?

A

To make it burn longer
To make the powder stick to it
To sterilise it and ensure results are accurate

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4
Q

What was the composition of Earth’s early atmosphere and why?

A

lots of CO2 and water vapour , steam, methane and ammonia because volcanoes were erupting releasing gases from inside the Earth
No oxygen because there was no metal oxides in layers of rock

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5
Q

What is the composition of the atmosphere now and what changed to cause this?

A

The magma cooled forming a thin layer of crust. The water vapour therefore condensed and fell as rain creating oceans.
Photosynthetic organisms evolved taking in O2 and releasing CO2 and some CO2 got locked up in fossil fuels and rocks
O2 increase
CO2 decrease

78% nitrogen
21% CO2
0.04% CO2
the rest is others

build of oxygen lead to the ozone layer blocking harmful rays from the sun and allowing more complex organisms to evolve

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6
Q

What is the test for oxygen?

A

If the gas will relight a glowing splint

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7
Q

What is the difference between the greenhouse gas effect, global warming and climate change?

A

Green house gas- We release greenhouse gases such as methane into the air by farming and CO2 by combustion. These get trapped in the atmosphere and when light rays try to bounce back to the atmosphere they are reflected back to Earth

Global warming - Is the gradual warming of our planet due to the reflection of light rays

Climate change - ice caps melting/ increase in average temperature / out of control weather

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8
Q

Discuss group 2?

A

As you go down the group they get more reactive because more shells mean there is bigger gap between the positive nucleus and negative electrons means there is a weaker electrostatic force so they react with other elements electrons more easily and lose their outer electron easier.

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9
Q

Discuss group 7?

A

The atoms at the top are more reactive because it has less shells so there isn’t as much shielding and the positive nucleus is closer to the electrons it wants to attract.

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10
Q

What is the calculation for percentage yield?

A

Percentage yield = actual yield / theoretical yield x100

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11
Q

How do you work our percentage yield if there is a reaction of 2Fe203 + 3C -> 4Fe + 3CO2
with 50kg or iron oxide and 18.9kg of iron

A
work out the relative formula mass for iron oxide and the relative atomic mass of iron
Mr (Fe2O3) = (2x56) + (3x16) = 160
Ar (Fe) = 56
Work out number of moles of iron oxide
(50 x 1000) divided by 160 = 312.5 moles

The equation tells you that 2 moles of iron oxide makes 4 moles of iron so 312.5 moles of iron oxide produces (312.5 / 2) x 4 = 625 moles of iron
Then work out the theoretical yield of your desired product (iron)
mass = moles x ar
625x56=35000g = 35kg
use equation and the actual yield of 18.9kg from question
18.9/35 x100 = 54%

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12
Q

Why do you never get 100% yield?

A

incomplete reactions
practical losses like transferring between containers
unwanted reactions
human error

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13
Q

What is the equation for atom economy?

A

atom economy = total Mr of desired products / total ?Mr of all products x 100

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14
Q

What does a high atom economy mean?

A

the higher the atom economy, the more reactants have been turned into desired and useful products

the higher the atom economy, the greener the process

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15
Q

Hydrogen gas can be made by…
Calculate the atom economy of the reaction:
CH4 + H20 -> CO + 3H2

A

identify the desired product (hydrogen gas H2)
calculate the Mr of all the prodcuts
Mr (CO) 12+16 = 28
Mr (3H2) 3x (1x2) = 6
28+6=34
Then work out the Mr of just the desired products
3 x Mr (H2) = 3 x (2x1) = 6
Use the formula to calculate atom economy
6/34 x100 = 18%

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16
Q

Why is a high atom economy better?

A

It doesn’t use up the products as quickly
Doesn’t maje waste materials that need to be disposed of
More profitable

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17
Q

What are some properties of transition metals?

A
Hard
Strong
Shiny
Malleable 
Good conductors of electricity and heat
High melting points
High densities 

Make good catalyst
Iron is the catalyst used in the haber process

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18
Q

What is an alloy?

A

Different size atoms so by mixing two different elements together it creates an irregular shape giving it strength

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19
Q

Describe alloys of iron (steels)?

A

Steel is made by adding small amounts of carbon to pure iron

Steel is harder than iron and stronger
Doesn’t corrode or rust

Bronze= copper+tine is harder tan copper and used for medals and statues
Brass = copper +zinc brass more maleable
Good alloys for jewellery because malleable and shiny
Aluminium alloys for aircrafts

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20
Q

What is rusting of iron ?

A

A redox reaction
Metals can corrode in the presence of oxygen and water to form their metal oxides
Corrosion of metals is caused by redox reactions where the metal loses electrons so its oxidised

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21
Q

What is iron seeding

A
Powdered iron into water 
Plants absorb to grow 
More plants more photosynthesis
CO2 down
O2 up
22
Q

OILRIG

A

Oxidation Is Loss

Reduction Is Gain of electrons

23
Q

What are ways to prevent rusting?

A

painting
oiling or greasing
sacrificial protection of adding another more reactive metal to react with the oxygen instead of what you want to protect
Galvanising - a coat of zinc is added because it is more reactive than iron and will lose electrons and corrode in preference to iron

24
Q

what conditions do you need to consider in an industrial process like the haber process?

A

cost of raw materials and wether it is economically

25
Q

what is the other test for metal ions other than the flame test?

A

add sodium hydroxide and a coloured precipitate forms

aluminium (AL3+) - white
calcium (Cl2+) - white
copper (Cu2+) - blue
Iron II (Fe2+) - Green 
Iron III (Fe3+) - Brown

To distinguish between aluminium and calcium you add sodium hydroxide in excess and aluminium goes colourless

26
Q

What is the test for the presence of ammonia ions?

A

add sodium hydroxide to the solution and gently heat, the gas given off will turn damp red litmus paper blue and will smell

27
Q

What is the test for halide ions?

A

2ml silver nitrate and 2ml of nitric acid
chloride - white
bromine - cream
iodide - yellow

28
Q

What is the test for carbonates?

A

Add dilute hydrochloric acid
the mixture will fizz if present because the carbonate will react with the acid to produce CO2 gas
Then run it through limewater and it will turn it milky if the gas is CO2

29
Q

What is the test for sulphate ions?

A

add dilute hydrochloric acid as it stops any reactions and precipitates forming that don’t involve sulphate ions
the add barium chloride
a white precipitate will form

30
Q

flame photometry was carried out on a sample know to contain calcium ions the measured wavelength emitted had an intensity of 4.5 use the curve to work out the concentration?

A

find the intensity on the y axis
travel along till you reach the curve
down to the x axis where conc is

31
Q

what is flame photometry and the advantages over flame tests?

A

an instrumental method that allows you to identify ions in a dilute solution

advantages: 
identify multiple ions in one mixture
very sensitive 
fast
accurate 
good if colourblind
32
Q

formula of first four alkanes?

A

CH4 METHANE
C2H6 ETHANE
C3H8 PROPANE
C4H10 BUTANE

33
Q

Formula of first four alkenes?

A

C2H4 ETHENE
C3H6 PROPENE
C4H8 BUT-1-ENE
C4H8 BUT-2-ENE

34
Q

What is the test for alkenes and alkanes?

A

bromine water

alkanes stay orange but alkenes turn colourless because the double bond opens up and reacts

35
Q
What are the uses for...
polyethene
polypropene 
polychlorethene
polytetrafluorethene
A

plastic bags, bottle, wire insulation
crates, garden furniture ,ropes
window frames, guttering, water pipes
non-stick pans and waterproof clothing

36
Q

what is condensation polymerisation?

A

involves two different types of monomers
at least two functional groups
for each new bond that is formed a small molecule of water is lost

COOH
OH

When the carboxylic group reacts with the alcohol group it forms and ester link

37
Q

formula for first four carboxylic acids?

A

HCOOH METHANOIC
CH3COOH ETHANOIC
C2H5COOH PROPANOIC
C3H7COOH BUTANOIC

38
Q

Formula for the first four alcohols ?

A

CH3OH METHANOL
C2H5OH ETHANOL
C3H 7OH PROPANOL
C4H9OH BUTANOL

39
Q

What happens when you oxidise an alcohol?

A

It forms a carboxylic acid

40
Q

Discuss the production of ethanol through the fermentation of ethane?

A

C6H12O6 -> 2C2H5OH + 2CO2
yeast used as a catalyst because of enzymes it contains
mix yeast and solution of carbohydrate in clean container, seal and leave in a warm place
30-40 degrees is optimum
must be done in anaerobic conditions otherwise the oxygen converts the ethanol into ethanoic acid
When the alcohol gets to around 20% it stops because the yeast gets killed off by the alcohol
yeast falls to bottom and you collect the ethanol from the top

41
Q

how do we contract a solution of ethanol above 20%?

A

fractional distillation
ethanol has a lower boiling point then water so the ethanol rises up the fractional distillation column and travels through the libeg condenser where it is condensed back down in a separate flask more concentrated

42
Q

how do you investigate what alcohols are better fuels?

A
  • put some alcohol in a spirit burner and measure mass of fuel and burner using mass balance
  • measure 100cm3 distilled water into a copper calorimeter and insulate with a draught excluder then cover with insulating lid with thermometer inside
  • take initial temp, put burner under calorimeter and light wick
  • stir using thermometer and when water has rise by 20 degrees blow out burner
  • reweigh burner and fuel
  • repeat with different alcohols

less alcohol burned in order to reach 20 degrees is the most efficient
longer the carbon chain the more effective

43
Q

properties of ceramics?

A
clay soft when dug up but can be hardened 
glass
strong 
mouldable
can be hardened
brittle
high mp and bp 
insulators of heat and electricity
don't degrade or corrde
hard wearing
44
Q

Composites

A

wood flooring

carbon fibre - light but strong

45
Q

properties of metals ?

A
good conductors of heat and electricity 
high density
malleable
corrosion resistant 
less brittle but may shatter
46
Q

properties of polymers?

A
flexible
cheap
easy moulded
less dense 
thermal and electrical insulators 
can degrade
47
Q

what affects the rate of reaction?

A
temperature
surface area
pressure
catalyst 
concentration 

rate of reaction is how long it takes for there to be a chemical change in something
the speed of reaction

48
Q

compound of 40% sulphur and 60% oxygen , empirical formula

A

40/32 = 1.25
60/16 = 3.75
1.25/1.25= 1
3.75/1.25=3 SO3

49
Q

what is the calculation for moles ?

A

mass = moles x formula mass

50
Q

calculate the mass of hydrogen produced when 72g of magnesium reacts with sulphuric acid?

A
Mr (mg) = 24 
Mr (mgSO4) = 24+32+(16x4) = 120
Mr (H2) = 2
72/24= 3 
h2 = 2x3 =6g