Enthalpy Definitions Flashcards

1
Q

Enthalpy change

A

heat transferred in a reaction at constant pressure

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2
Q

Exothermic

A

energy released to surroundings (-ve)

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3
Q

Endothermic

A

takes energy from surroundings(+ve)

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4
Q

standard enthalpy change of reaction

A

reaction happens in molar quantities shown in reaction

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5
Q

standard enthalpy change of formation

A

1 mole of a compound is formed from its elements

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6
Q

standard enthalpy change of combustion

A

1 mole of substance is completely burned in oxygen

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7
Q

standard enthalpy change of neutralisation

A

1 moles of water is formed from neutralising H ions by OH ions

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8
Q

standard enthalpy of atomisation

A

1 mole of an element is converted to gaseous atoms

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9
Q

average bond enthalpy

A

enthalpy change when 1 mole of a bond is broken into separate gaseous atoms

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10
Q

Hess’s Law

A

enthalpy change is independent o the route by which the reaction takes place

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11
Q

Why is experimental combustion enthalpy less exothermic than that given in data books?

A

Any out of:

  • Heat lost to surroundings
  • Incomplete combustion
  • Evaporation of fuel (after weighing)
  • Incomplete transfer of heat
  • Heat absorbed by calorimeter
  • Measurements not carried out in standard conditions
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