Enthalpy Definitions Flashcards
Enthalpy change
heat transferred in a reaction at constant pressure
Exothermic
energy released to surroundings (-ve)
Endothermic
takes energy from surroundings(+ve)
standard enthalpy change of reaction
reaction happens in molar quantities shown in reaction
standard enthalpy change of formation
1 mole of a compound is formed from its elements
standard enthalpy change of combustion
1 mole of substance is completely burned in oxygen
standard enthalpy change of neutralisation
1 moles of water is formed from neutralising H ions by OH ions
standard enthalpy of atomisation
1 mole of an element is converted to gaseous atoms
average bond enthalpy
enthalpy change when 1 mole of a bond is broken into separate gaseous atoms
Hess’s Law
enthalpy change is independent o the route by which the reaction takes place
Why is experimental combustion enthalpy less exothermic than that given in data books?
Any out of:
- Heat lost to surroundings
- Incomplete combustion
- Evaporation of fuel (after weighing)
- Incomplete transfer of heat
- Heat absorbed by calorimeter
- Measurements not carried out in standard conditions