Enthalpy Changes Flashcards

1
Q

Define enthalpy

A

the heat content stored in a chemical system

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2
Q

How is energy given out in a chemical system after bonds in reactants break?

A

Energy is given out when new bonds form in the product.

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3
Q

What is the reaction called when energy is needed to break bonds, which is then released when these bonds are made?

A

endothermic reaction

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4
Q

In a reaction, if more energy is used when bonds are made then taken in when bonds are broken. What type of reaction is it?

A

endothermic reaction

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5
Q

What can help illustrate enthalpy changes in reaction?

A

Enthalpy profiles

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6
Q

What does an exothermic reaction enthalpy profile show?

A

it shows that the enthalpy of the products is lower than the enthalpy of the reactants.
It also shows that heat is given out to the surroundings.

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7
Q

What does an endothermic reaction enthalpy profile show?

A

In endothermic reactions, the enthalpy of the products is greater than that of the reactants.
This also shows that heat is absorbed from the surroundings.

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8
Q

What does enthalpy refer to?

A

heat energy

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9
Q

Do reactions happen spontaneously?

A

They don’t tend to

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10
Q

What is needed to start a reaction?

A

An input of energy.

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11
Q

What is that input energy called to start a reaction?

A

Activation Energy

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12
Q

What can enthalpy profiles show with the activation energy in both endothermic and exothermic reactions?

A

The amount of activation energy needed for both reactions to occur and the difference in the energy for both reactions

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13
Q

Define standard enthalpy change of formation

A

the enthalpy change that occurs when one mole of a compound forms from its elements under standard conditions.

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14
Q

Define standard enthalpy change of combustion

A

the enthalpy change that occurs when one mole of a compound completely combusts in oxygen under standard conditions

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15
Q

Define standard enthalpy change of neutralisation

A

the enthalpy change that occurs when an acid is neutralised by a base forming one mole of water under standard conditions.

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16
Q

Define standard enthalpy change of reaction

A

the enthalpy change that occurs in the molar quantities expressed in the equation under standard conditions

17
Q

How do you measure enthalpy change? (combustion)

A

Measure the temperature change

18
Q

How do you calculate enthalpy change?(combustion)

A

Work out the amount of heat energy transferred from the fuel of water.
Calculate the number of moles that have been burned to produce the energy

19
Q

Define mean bond enthalpy ?

A

the energy required to break 1 mole of a specified type of bond in a gaseous molecule.

20
Q

The amount of energy it takes to break a wide variety of bond. is the?…….

A

it is the average

21
Q

Define Hess’s Law

A

The total enthalpy change for a chemical reaction is independent of the route by which the reaction is achieved.

22
Q

What does hess’s law allow us to do?

A

it allows us to find enthalpy changes that cannot be measured directly, using existing enthalpy change values and enthalpy cycle diagrams.

23
Q

What can hess’s law cycles be used for?

A

show the standards of enthalpies of formation.