enthalpy change Flashcards

1
Q

what is H

A

enthalpy, measure of the het energy in a chemical system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is the chemical system?

A

refers to the atoms molecules , or ions making up the chemicals.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

enthalpy change?

A

= H(products)- H(reactants)

change in H can be negative or positive dependin on whether the products contain more or less energy than the reactants.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

law of conservation of energy ?

A

states that energy cannot be created or destroyed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

. what is the system in. chemical reaction involving enthalpy changes?

A

system- the chemicals - the reactants and the products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

whats the surroundings in a chem reaction involving enthalpy changes?

A

surroudnings- the apparatus, the laboratory and evrything thats not the chem system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

exothermic reaction

A

energy transferred from the system to the surroundings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

endothermic reaction

A

energy transferred from surroundings to the system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

activation energy

A

minimum energy required for a reaction to take place

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

units for standard enthalpy change?

A

KJmol^-1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

standard pressure?

A

100 kpa

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

standard temp ?

A

298K (25 dc)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

standard concentration?

A

1mol dm^-3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

standard state?

A

the physical state of a substance under standard conditions - 100 kPa and 298K

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

standard enthalpy change of reaction?

A

the enthalpy change that accompanies a reaction in molar quantities shown n the chemical equation under standard cond. with all products and reactants in their standard states.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

standard enthalpy change of formation ?

A

the enthalpy change that takes place when ONE mole of a compound is FORMED FROM ITS ELEMENTS under standard conditions, with all reactants and products in their standard states.

17
Q

enthalpy change of combustion ?

A

enthalpy chnge that takes place when one mol of a substance reacts completely with oxygen under standard conditions, with all reactants and products in their stand. states.

18
Q

enthalpy change of neutralisation

A

energy change that accompanies the reaction of an acid by a base to form one mole of H2O (l) udner stand. cond. with all reactants and products in their standard states.

19
Q

0 kelvins in degrees cels.

A

-273 degrees

20
Q

why is a 1k rise in temp the same as 1 degrees rise in temp ?

A

if use a thermometer graduated in degrees celsius the value of temp change is exacly the same in degrees and K

21
Q

specific heat capacity (c)

A

energy required to raise the temp of 1g of a substance by 1K

22
Q

what is the c of water

A

4.18Jg^-1K^-1

23
Q

equation for calculating (heat energy change (q))?

A

mass x c x change in temp

24
Q

why may less heat be transferred to water in na experiment that tests the enthalpy change of combustion of methanol ?

A

heat loss to surroundings otehr than water
incomplete comb. of methanol
evaporation of methanol from the wick
non-standard conditions