Buffer solutions Flashcards
buffer solution
a system that minimises pH changes when small amounts of acid and a base are added.
- consists of two components to remove an added acid/ alkali; a weak acid and a conjugate base.
preparation of weak acid buffer solutions
1) Weak acid from salt
mis solution of ethanoic acid CH3COOH and CH3COONa Sodium ethanoate.
- Add ethanoic acid to water = partially discssociates and amount of ethanoate ions in solution is very small.
- CH3COOH ⇌ H+ + CH3COO-
- salts of weak acids are ionic compounds so prov
why r salts of weak acids convenient sources of conjugate bases?
salts of weak acids are ionic compounds ; when added to water the salt completely dissolves , dissociation into ions is complete so a source of conj base component.
2) Weak acid buffer solution from strong alkali .
adding aqueous solution of an lakali such as NaOH to an excess of the weak acid.
Weak acid is partially neutralised by alkali ; forms conj base (salt of weak acid) and since weak acid is in excess there is some of weak acid left over unreacted.
result ; mixture of salt of weak acid an dany unreacted weak acid.