Enthalpy And Entropy Flashcards
Is lattice enthalpy positive or negative
Negative
What is the layout of a born haber cycle
Charged gaseous ions
Gaseous atoms
Elements in standard states
Ionic lattice
What is 🔼atH
The enthalpy change when one mole of gaseous atoms are formed from the element in standard state and conditions
What is 🔼EAH
He enthalpy change when one mole of gaseous atoms each gain an electron to form one mole of gaseous -1 ions
Is a more negative lattice stronger
Yes
Is the first electron affinity negative
Yes
Is the second electron affinity negative
No
What is 🔼solH
The enthalpy change when one mole of solute dissolves in a solvent
What is the 🔼hyd H
The enthalpy change when one mole of gaseous ions become dissolved Into water to form one mole of aqueous ions
Dissolving process diagram
Gaseous ions
Hydration Aqueous ions Dissolving
Ionic lattice Up
What are the properties of ionic compounds
High melting point
Soluble in polar solvents
Conduct electricity when aqueous or molten
Factors affecting lattice enthalpy
Ionic size
Ionic charges
Factors affecting hydration
Ionic radius (the larger the less negative, attraction between ion and water decreases) Ionic charge (as increases more negative as attraction between water and ion increases)
When will an ion dissolve
If the sum of the hydration enthalpies is greater the enthalpy charge of the solution
No depends on temperature and entropy
What are the units for energy
J K-1 mol-1
What have the smallest enthalpies
Solid
If a system becomes more disordered what type of change will there be
Positive
What is the unit for standard entropies
J K-1 Mol-1
Calculating entropy changes
🔼s products = s products-s reactants
What is Gibbs free energy equation
🔼G= 🔼H-T🔼S
What must 🔼G be to be feasible
<0
What does T equal
🔼H/🔼S
🔼H 🔼S T 🔼G
Negative Positive Low/high ?
Negative
🔼H 🔼S T 🔼G
Positive Negative Low/high ?
Positive
🔼H 🔼S T 🔼G
a) . Negative. Negative. Low.
b) . Negative. Negative. High
Negative
Positive
🔼H 🔼S T 🔼G
a) . Positive. Positive. Low
b) . Positive. Positive. High
Positive
Negative
Problems with feasibility
Doesn’t take into account activation energy
Standard conditions