Energy Changes Flashcards
What is an exothermic reaction
A reaction that transfers energy to the surroundings, usually by heating
Shown by rise in temperature
Examples of exothermic reactions
Combustion (burning fuels)
Neutralisation reactions
Oxidation reactions
Uses of exothermic reactions in everyday life
Hand warmers
Self heating cans of hot chocolate and coffee
What is an endothermic reaction
A reaction which takes in energy from surroundings
Shown by fall in temperature
Examples of endothermic reactions
Citric acid with sodium hydrocarbonate
Thermal decomposition
Uses of endothermic reactions in everyday life
Sports injury ice packs
How do you test the effect of acid concentration on the energy released in a neutralisation reaction between HCL and NaOH (required practical)
Put 25cm^3 of 0.25 mol/dm^3 HCL and NaOH in separate beakers
Place beakers in a water bath at 25 degrees until both are at same temperature
Add both liquids to a polystyrene cup with lid
Take the temperature of mixture every 30 seconds and record highest temperature
Repeat using 0.5mol/dm^3 and then 1 oml/dm^3 of HCL and record temperatures
What is the biggest problem with energy measurement experiments, and how can this be reduced
The problem is energy is often lost to the surroundings and this isn’t recorded
Can be reduced by putting polystyrene cup into a beaker of cotton wool to give more insulation and put lid on cup to reduce energy loss by evaporation
What is a reaction profile
A diagram that shows the relative energies of the reactants and products in a reaction and how the energy changes over the course of the reaction
What is activation energy and what does it show
It is the minimum amount of energy the reactants need to collide with each other and react.
The greater it is, the more energy needed to start the reaction, this has to be supplied eg by heating the reaction mixture
What does an exothermic reaction profile show
The difference in height represents the overall energy change in the reaction (energy given out) per mole
The initial rise in energy represents the energy needed to start the reaction (activation energy)
What does the endothermic reaction profile show
The products are at a higher rate than the reactants (absorbs energy)
The difference in height represents the overall energy change during the reaction (energy taken in)
Energy must be supplied to break existing bonds, is bond breaking an endothermic process or exothermic
Endothermic
Is bond formation exothermic or endothermic and why
Exothermic because energy is released
How do you calculate the overall energy change in bond energy calculations
Sum of energies needed to break bonds in the reactants minus the energy released when new bonds are formed