Energy and Metabolism Flashcards

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1
Q

The break down of large complex molecules into smaller ones is called _________. The build up into large molecules is called _______. The sum of these two processes is called ________.

A

catabolism, anabolism, metabolism

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2
Q

Energy that organisms use to do work comes in many forms, such as light, sound and electricity. All energy forms can be classified as either _________ (energy possessed by moving objects) or __________ (stored energy).

A

Kinetic, potential

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3
Q

Give examples of kinetic energy. Give examples of potential energy.

A

Kinetic: boy kicking a soccer ball, spindle fibres moving, heart muscle contracting

Potential: a raised weight, ripe fruit before it falls, diver on top of a diving board

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4
Q

Gravitational potential energy is the __________ between two objects. Chemical potential energy is the attraction of _________ to _________ in a chemical bond.

A

attraction, electrons, protons

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5
Q

The First Law of Thermodynamics states that the total amount of energy in the universe is _________. Energy can not be _________ or destroyed.

A

constant, created

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6
Q

Molecules possess stability because of the chemical ________ between their atoms. When atoms form covalent bonds, there is greater _______. However, some bonds are more ________ than others.

A

binds, stability, stable

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7
Q

Bond energy measures the ________ of a covalent bond. It is equal to the minimum amount of energy required to break one _____ of bonds between two types of atoms. The ________ the bond energy is, the harder it is to break the bond.

A

stability, mole, higher

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8
Q

Energy is _______ when reactant bonds break and energy is ________ when product bonds form. If the bonds in the products are more stable than the ______, more energy is RELEASED and thus the reaction is _________. If the amount of energy absorbed to break reactant bonds is greater than that used to make product bonds, the reaction is __________.

A

absorbed, released, reactants, exothermic, endothermic

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9
Q

The overall change in energy that occurs in a reaction is symbolized by ____ and is called a change in _______. Postive H is _________ reaction and negative is ________.

A

H, enthalpy, endothermic, exothermic

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10
Q

The Second Law of Thermodynamics states that the overall _______ of the universe is always increasing. Entropy is a quantitative value that measures the degree of __________. It increases during any __________ reaction.

A
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11
Q

Although the universe tends toward _______, living organisms can expend energy is establish and maintain __________ structures. Ex amino acids synthesizing together to form _________.

A

disorder, orderly, proteins

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12
Q
A
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13
Q

Chem reactions that help maintain order release waste as ________ energy and by-products of metabolism (______ ________). Thus, the entropy of an organism can _______ while the entropy of the universe _________.

A

thermal, carbon dioxide, decrease, increase

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14
Q

_________ reactions will occur on its own once it is underway. ______________ need a continual input of energy.

A

Spontaneous, non-spontaneous

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15
Q

Increase in entropy, exothermic: _________ at all temps (burning wood), endothermic: ________ at high temps (sweat evaporating from skin)

Decrease in entropy, exothermic: __________ at low temps (water freezing), endothermic: ___ ___________ at any temp (formation of diamonds)

A

spontaneous, spontaneous, spontaneous, non-spontaneous

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16
Q
A
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17
Q

Some energy is lost in a reaction (increases _________), but the portion not lost that is still there to do work in a system is called _______ _________. It is represented by the symbol _____.

A

entropy, free energy, G

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18
Q

The change in free energy (delta G) is represented by G final state - G initial state. Reaction with a negative G give ______ free energy, and those with a positive value _______ free energy. Thus, negative is ________ and positive is ____________.

A

off, absorb, spontaneous, non-spontaneous

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19
Q

-273 degrees Celcius is equal to ______ Kelvin.

A

zero.

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20
Q

Free energy is ________ energy, Therefore burning paper and using the energy to boil water would be an example of ______ energy. Using it just to be released into the atmosphere is not.

A

useful, free

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21
Q

Exergonic reactions are ________, release free energy and endergonic reations ___________ free energy (in the products). In which reaction is ATP in the products?

A

spontaneous, non-spontaneous. ATP is in the products during exergonic

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22
Q

Energy coupling is when exergonic reactions ________ free energy, which is then used to _______ endergonic reactions that require energy. All ___________ reactions are coupled to ___________ reactions. Energy reqruired by and endergonic reaction is ______ than energy released by the coupled reaction.

A

release, drive, endergonic, exergonic, less

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23
Q

Glucose has too much _________. It is broken down into smaller ______ molecules, each carrying a small amount of _______.

A

energy, ATP, energy

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24
Q

ATP supples _______ energy to do useful _______ in the body. For example, transport ions, contract muscles, beat cilia

A

free, work

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25
Q

The ___________ of ATP into ADP is a __________ process and releases free _______ which does useful work in the body.

A

hydrolysis. exergonic, energy

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26
Q

Phosphorylation is the process of attaching a _________ group to an organic molecule resulting in the _______ of free energy, reducing its ________ and therefore making it more active.

A

phosphate, gain, stability

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27
Q

What happens to electrons in an oxidation reaction? Reduction reaction? (gained/lost?) Thus what is a redox reaction?

A

Oxidation: lost

Reduction: gained

Redox: transfer of electrons

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28
Q

Good fuel molecules contain a great deal of _________ energy. It is later converted to _______ energy.

In this way, gasoline and glucose both are good fuel bc they have a lot of ________ in the form on C-H bonds

A
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29
Q

Electrons farther away from the nucleus have more chemical energy. Why?

A

It takes chemical energy to move up energy levels

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30
Q

Our food must undergo which chemical reaction for us to obtain energy? In this way, food is a ________ agent.

A

oxidation. Food is a reducing agent

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31
Q

Reducing and oxidizing agents do not care about ________, they care about other people! So, an oxidizing agent, causes _______, but itself is _________.

A

themselves, oxidizing agent oxidizes, but itself is reduced

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32
Q

What is a dehydrogenase?

A

An enzyme that oxidizes a substrate and transfers electrons to energy carriers

33
Q

What are energy carriers?

A

Small molecules that readily cycle between oxidized and reduced forms and are used to transport electrons

34
Q

NAD+ is an electron carrier. it is reduced to NADH by gaining 2 _______ and one H_ (+/-). NADH is ________ (gaining/losing) energy.

A

2 electrons, H+, gaining

35
Q

What is aerobic respiration? What is the difference between an obligate aerobe and anaerobe?

A

Process that uses oxygen to use energy from organic compounds. Aerobes cannot live without oxygen, anaerobes can!

36
Q

What are the 4 stages of cellular respiration?

A

glycolysis, pyruvate oxidation, citric acid cycle, electron transport chain

37
Q

What is the overall equation of cellular respiration?

A

Glucose + oxygen = carbon dioxide + water

38
Q

Which step of cellular respiration occurs in the inner mitochondrial membrane? A majority of what is made?

A

Electron transport chain

39
Q

What two steps of cellular respiration occur in the matrix (middle) of the mitochondria?

A

citric acid cycle and pyruvate oxidation

40
Q

Glycolysis breaks down ________. Does it require oxygen?

A

glucose, NO OXYGEN REQUIRED

41
Q

In step 3 of glycolysis, ATP is broken down by an allosteric enzyme. What does allosteric mean?

A

Allosteric indicates the enzyme changes its shape to accommodate the substrate

42
Q

Reaction 5 of glycolysis includes the interchanging between ______ and _____ bc they are isomers of each other. Eventually they all become ______.

A

G3P, DHAP, G3P

43
Q

The final products of glycolysis are the 3 2s. What are they?

A

NADH, ATP, Pyruvate

44
Q

Pyruvate is originally 3 ______. During pyruvate oxidation, a _______ group is snipped off of ______. It is released as ____.

A

carbons, carboxyl, pyruvate, CO2

45
Q

During pyruvate oxidation, a 2-carbon molecule is ________ and its electrons are picked up by NAD+ to form ______.

A

oxidized, NADH

46
Q

The oxidized 2 carbon molecule is an ______ group. It attaches to Coenzyme A (CoA), a molecule derived from vitamin ___5 to form acetyl CoA

A
47
Q

Acetyl CoA is sometimes called a carrier molecule. Its job is to carry ______ to the citric acid cycle.

A

acetyl group

48
Q

All reactions in the citric acid cycle are _______ and occur in the _____ of the mitochondria.

A

exergonic, matrix

49
Q

Reactions 3 and 4 of the citric acid cycle are coupled, _______ reactions. They loose a carboxyl group, and this is called _____________.

A

redox, decarboxylation

50
Q

The Krebs cycle produces ___ ATP, ___ NADH, ___ FADH2, CO2 for every glucose. This entails ___ turns of the Krebs cycle.

A

2 ATP, 6 NADH, 2 FADH, 4 CO2, 2 TURNS

51
Q

The reduced electron carriers made in the citric acid cycle carry their _______ to the ______ _______ ________. There, most of the ATP is synthesized via _________ ___________.

A

electrons, electron transport chain, oxidative phosphorylation

52
Q

At the beginning of the citric acid cycle, 4-carbon acceptor molecule, _________ combines with Acetyl CoA to form ______. (6 carbons)

A

oxaloacetate, citrate

53
Q

In the ETC, NADH is oxidized by complex 1 and looses ___ electrons. Complex 1 has a higher ____________ than NADH.

A

2 electrons, electronegativity

54
Q

The free energy released by the movement of electrons in the ETC is used to actively transport ____ from the matrix to the ____________ space.

A

H+, inter membrane

55
Q

Oxygen takes the last e- from complex ____ so that the cycle can repeat.

A

complex 4

56
Q

H+ comes back through a channel protein called ATP __________. This diffusion from high to low is __________ (ender/ exer) and drives the synthesis of ATP

A

synthase, exergonic

57
Q

For each NADH oxidized via the ETC, ____ ATP are made. For each FADH2, _____ ATP are made.

A

NADH - 3, FADH2 -2

58
Q

Only _______ cell have the ability to transfer 2 NADH into the ____________ without converting them to FADH2 first. (2 x ___ ATP for muscle cells, 2 x __ ATP for all other cells)

A

muscle, mitochondria, 3, 2

59
Q

Cyanide is _______. It binds to the complex ____ of ETC and prevents cells from using ______.

A

deadly, complex 4, oxygen

60
Q

_____ and _____ are allosteric inhibitors and glycolysis. If either of their levels are too ______, which allosteric enzyme slows glycolysis down?

A

ATP and citrate, high, phosphofructokinase

61
Q

ADP is an allosteric ________ is glycolysis that stimulates ____________ (the enzyme) to make more ATP

A

activator, phosphofructokinase

62
Q

What is beta-oxidation?

A

process by which fatty acids break down into Acetyl-CoA which can enter the Krebs cycle

63
Q

_________ is produced during lactic acid fermentation. Why?

A

Lactate. Oxygen being supplied to the mitochondria is not enough to meet every demands

64
Q

Lactic acid fermentation usually happens during _______.

A

excersize

65
Q

During lactic acid Ferm, glycolysis is happening so fast that excess ______ is made. This excess is made right into _______. This oxidizes NADH into NAD_, a carrier used to maintain a high rate of ________.

A

During lactic acid Ferm, glycolysis is happening so fast that excess pyruvate is made. This excess is made right into lactate. This oxidizes NADH into NAD+, a carrier used to maintain a high rate of glycolysis.

66
Q

What are the two stages of photosynthesis? Where do they occur?

A
  1. Light-dependant reactions: occurs in the thylakoid of a chloroplast
  2. Calvin cycle: occurs in stroma of chloroplast
67
Q

Be familiar with this diagram of a chloroplast. What is the diff between stroma and lumen?

A

Stroma is the inside of a chloroplast. Lumen is the inside of a thylakoid.

68
Q

Breaking news: a photon has been absorbed by an excitable electron on an atom that is apart of a pigment. As it moves from a low energy level to a high? What are its three fates?

A
  1. electron returns to ground state by emitting light at lower wavelength (fluorescence)
  2. electron returns to ground state and energy is transferred to a diff pigment
  3. excited state electron itself is transferred to a nearby primary electron acceptor
69
Q

What is the difference between the action and absorption spectrum?

A

Absorption spectrum indicates wavelengths of light absorbed by each pigment.

Action spectrum indicates the overall rate of photosynthesis at each wavelength of light

70
Q

The colour of a pigment tells you the colour it ______ NOT absorbs. Therefore, things that appear white ______ everything.

A

reflect, white reflects everything!

71
Q

Knowing that colours reflect light, why is chlorophyll A darker than chlorophyll B?

A

Chlorophyll A reflects more blue light, therefore it appears darker than B

72
Q

What are photosynthetic pigments? where are they found and how many are in each group?

A

Organic molecules w the ability to absorb energy from the sun. found in thylakoids in groups of 300-400

73
Q

what are groups of thylakoids w photosynthetic pigments called?

A

antenna complex

74
Q

During photosynthesis, how does chlorophyll a donate an excited electron? Who does it go to?

A

Chlorophyll a is oxidized. It goes to the primary electron acceptor

75
Q

Accessory pigments, also known as the ________ ________ are made up of which two pigments.

A

antenna complex, made up of chlorophyll b and carotenoids

76
Q

Accessory pigments transfer excitation energy from light to _________ in the ______ centre.

A

chlorophyll a, reaction centre

77
Q

The antenna complex that its found in every photosystem is also called what?

A

Light harvesting complex

78
Q

What is the final thing that receives an excited electron? Where passed along?

A

Primary electron acceptor. It is passed along an electron transport chain.