energy and enzymes Flashcards

1
Q

when do chemical reactions occur?

A

when atoms have enough stored energy to combine or change bonding patterns

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2
Q

what is metabolism

A

sum total of all chemical reactions occurring

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3
Q

what are the two types of metabolic reactions

A

anabolic and catabolic

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4
Q

what are anabolic reactions

A

the building of complex molecules from simple molecules (condensation)

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5
Q

what are catabolic reactions

A

simple molecules being broken down from complex molecules (hydrolysis)

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6
Q

what is energy

A

the capacity to do work or the capacity for change

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7
Q

the energy released in ________ is used to drive _________ to do ___________

A

catabolic reactions, anabolic reactions, biological work

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8
Q

what is free energy

A

the usable energy for work

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9
Q

what are exergonic reactions

A

release of free energy, -G, spontaneous, hydrolysis, catabolism

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10
Q

what are endergonic reactions

A

consume free energy, +G, non spontaneous, condensation, anabolism

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11
Q

what is the energy amount required to get a reaction to proceed called

A

activation energy

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12
Q

is activation energy greater for exergonic or endergonic reactions

A

exergonic

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13
Q

what is the transition state?

A

an unstable higher energy state

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14
Q

what do enzymes do?

A

also known as catalysts, they lower the activation energy and therefore increase the rate of chemical reactions, stabilize the transition state

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15
Q

what type of macromolecule are enzymes usually

A

proteins, highly specidic

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16
Q

do enzymes participate in the catalytic process?

17
Q

what enzymes break down carbs

A

amylase, sucrase, lactase, or maltase

18
Q

what enzymes break down proteins

A

trypsin, pepsin, peptidase, and others

19
Q

what enzyme breaks down lipids

20
Q

what does sucrase break down

A

sucrase breaks down sucrose (disaccharide) into glucose and fructose (monosaccharides)

21
Q

is the activation energy larger for exergonic or endergonic reactions

A

endergonic

22
Q

why mist endergonic reactions be coupled with exergonic reactions

A

to overcome the energy barrier. This makes the net free-energy change to be negative less than 0.

23
Q

where is energy stored

A

it is stored in ATP and is harnessed to join two molecules together

24
Q

What is ATP

A

adenosine triphosphate, it captures and transfers free energy (activated carrier)

25
What does ATP get hydrolyzed into
ADP and P which realeases a lot of energy for endergonic reactions
26
What characteristics of ATP account for the free energy released
A) ATP has three phosphate groups that repel each other because of their negative charges. The energy needed to get them close enough to bond is stored in the P-O bond. B) The free energy of the P-O bond is higher in energy that the OH bond that is formed after hydrolysis therefore releasing energy
27
Calles often harness energy released from ______ to fuel regeneration of ____ from ____
exergonic, ATP, ADP + P
28
What are the steps of reaction coupling
1) Activation: ATP transfers a phosphate, P, to A-OH to produce a high-energy intermediate 2) Condensation: the activated intermediate reacts with B-H to form a product A-B along with the release of inorganic phosphate and ADP
29
what is reaction coupling used for
used by the cell to drive reactions