empirical formula Flashcards
what is meant by the empirical formula of a compound?
the simplest whole number ratio of the different atoms that are present in the compound
where in the electromagnetic spectrum does the vibrational frequency of atoms lie?
infrared region (IR)
atoms in organic molecules can absorb infrared radiation, what happens to the molecule when this occurs?
causes part of the molecule to vibrate but not break
how can molecules vibrate?
by bending and stretching
What does NMR stand for?
Nuclear Magnetic Resonance
True or False: Infrared spectroscopy is used to identify functional groups in a molecule.
True
Fill in the blank: NMR spectroscopy provides information about the __________ environment of atoms in a molecule.
chemical
What is the principle behind NMR spectroscopy?
It is based on the absorption of radiofrequency radiation by nuclei in a magnetic field.
Which type of nuclei are commonly analyzed using NMR?
Hydrogen-1 (¹H) and Carbon-13 (¹³C)
Multiple choice: What does the chemical shift in NMR indicate?
The electronic environment surrounding a nucleus.
True or False: Higher chemical shifts in NMR indicate a more shielded nucleus.
False
What is the role of the Fourier Transform in NMR?
To convert raw data into a spectrum.
Fill in the blank: Infrared spectroscopy measures the __________ of a molecule.
vibrational transitions
What type of radiation is used in infrared spectroscopy?
Infrared radiation
Multiple choice: Which region of the infrared spectrum is typically used for organic compounds?
Mid-infrared region (4000-400 cm⁻¹)
True or False: The peaks in an IR spectrum correspond to the frequencies of molecular vibrations.
True
What information can be derived from the area under a peak in an NMR spectrum?
The relative number of protons contributing to that peak.
Fill in the blank: In NMR, coupling patterns provide information about the __________ of neighboring nuclei.
number
What is the significance of the fingerprint region in an IR spectrum?
It provides unique identification for a molecule.
Multiple choice: Which of the following functional groups shows a strong absorption around 1700 cm⁻¹ in IR spectroscopy?
Carbonyl (C=O)
True or False: NMR can be used to determine the stereochemistry of a molecule.
True
What does the term ‘splitting pattern’ refer to in NMR?
The pattern of peaks resulting from interactions between neighboring nuclei.
Fill in the blank: The __________ rule helps predict the splitting pattern in NMR.
n+1