empirical formula Flashcards

1
Q

what is meant by the empirical formula of a compound?

A

the simplest whole number ratio of the different atoms that are present in the compound

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2
Q

where in the electromagnetic spectrum does the vibrational frequency of atoms lie?

A

infrared region (IR)

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3
Q

atoms in organic molecules can absorb infrared radiation, what happens to the molecule when this occurs?

A

causes part of the molecule to vibrate but not break

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4
Q

how can molecules vibrate?

A

by bending and stretching

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5
Q
A
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6
Q

What does NMR stand for?

A

Nuclear Magnetic Resonance

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7
Q

True or False: Infrared spectroscopy is used to identify functional groups in a molecule.

A

True

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8
Q

Fill in the blank: NMR spectroscopy provides information about the __________ environment of atoms in a molecule.

A

chemical

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9
Q

What is the principle behind NMR spectroscopy?

A

It is based on the absorption of radiofrequency radiation by nuclei in a magnetic field.

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10
Q

Which type of nuclei are commonly analyzed using NMR?

A

Hydrogen-1 (¹H) and Carbon-13 (¹³C)

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11
Q

Multiple choice: What does the chemical shift in NMR indicate?

A

The electronic environment surrounding a nucleus.

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12
Q

True or False: Higher chemical shifts in NMR indicate a more shielded nucleus.

A

False

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13
Q

What is the role of the Fourier Transform in NMR?

A

To convert raw data into a spectrum.

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14
Q

Fill in the blank: Infrared spectroscopy measures the __________ of a molecule.

A

vibrational transitions

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15
Q

What type of radiation is used in infrared spectroscopy?

A

Infrared radiation

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16
Q

Multiple choice: Which region of the infrared spectrum is typically used for organic compounds?

A

Mid-infrared region (4000-400 cm⁻¹)

17
Q

True or False: The peaks in an IR spectrum correspond to the frequencies of molecular vibrations.

18
Q

What information can be derived from the area under a peak in an NMR spectrum?

A

The relative number of protons contributing to that peak.

19
Q

Fill in the blank: In NMR, coupling patterns provide information about the __________ of neighboring nuclei.

20
Q

What is the significance of the fingerprint region in an IR spectrum?

A

It provides unique identification for a molecule.

21
Q

Multiple choice: Which of the following functional groups shows a strong absorption around 1700 cm⁻¹ in IR spectroscopy?

A

Carbonyl (C=O)

22
Q

True or False: NMR can be used to determine the stereochemistry of a molecule.

23
Q

What does the term ‘splitting pattern’ refer to in NMR?

A

The pattern of peaks resulting from interactions between neighboring nuclei.

24
Q

Fill in the blank: The __________ rule helps predict the splitting pattern in NMR.

25
What does the term 'downfield' mean in NMR?
A region of higher chemical shift values.
26
Multiple choice: Which instrument is used to perform NMR spectroscopy?
NMR spectrometer
27
True or False: IR spectroscopy can provide information about the molecular weight of a compound.
False
28
What is the main advantage of using NMR over other spectroscopic techniques?
It provides detailed information about molecular structure and dynamics.
29
Fill in the blank: The __________ of a molecule can be inferred from its IR spectrum.
functional groups
30
What is a common solvent used in NMR spectroscopy?
Deuterated solvents (e.g., D₂O, CDCl₃)
31
Multiple choice: In IR spectroscopy, which type of bond typically absorbs at a higher frequency?
Stronger bonds (e.g., triple bonds)