Elements from the sea(ES) Flashcards
What factors can affect the position of equilibrium?
Concentration, pressure and temperature
What is meant by ‘dynamic equilibrium’
A reversible reaction which takes place in a closed system. The rate of the foward reaction is equal to the rate of the backwards reaction. Concentrations remain constant
What happens to the position of eqm if temperature:
-Increases
-decreases
-Increases=direction of the endothermic reaction
-Decreases=direction of the exothermic reaction
What happens to the position of eqm if the pressure
-Increases
-Decreases
-Increases=Side with fewer gas molecules
-Decreases=Side with more gas molecules
Why don’t catalysts affect the position of eqm?
Catalysts only increase the rate of the foward and backward equation equally. Therefore they don’t affect the position of eqm
What is the other name for group 7 elemants?
Halogens
What bond is formed between two group 7 elements?
Covalent
What is the appearance of Fluorine,Chlorine, Iodine and bromine at room temperature?
- Fluorine~pale yellow gas
- Chlorine~green gas
- Bromine~dark red volatile liquid
- Iodine~shiny black solid
What happens as you go down group 7?
- Becomes darker in colour
- Melting and boiling points increase
- Become less volatile
Are halogens more soluble in water or organic solvents e.g. hexane
Orgainc solvents~this means that in organic solvents halogens have a much more distinct colour
Size of the atom
Why is fluorine a stronger oxidisng agent than chlorine?
- F atoms are smaller=attraction between nucleus and outer electron is very strong
- This attraction is weaker in Cl
- This means that F gains an extra electron more readily to become a negative ion than Cl
What is the reaction between a halogen and a halide?
Displacement reaction
Why does a displacement reaction happen?
A halogen displaces a less reactive halogen from the compound
What is the test for halide ions?
Add silver nitrate solution then ammonia to distinguish between the halides
What is precipitate of chloride,bromide and iodide when silver nitrate is added?
- Chlorine~White
- Bromine~Cream
- Iodine~Pale yellow