Electronegativity, Polarity And Bonding+ Shapes Of Molecules Flashcards

1
Q

Definition of electronegativity

A

It is the ability of an to attract a pair of electrons towards itself in a covalent bond

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2
Q

How does nuclear charge affect electronegativity

A

An increase In Number of protons leads to increase in nuclear attraction for the electrons in the outer shell. So an increase nuclear charge results in an increased electronegativity

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3
Q

How does atomic radius affect electronegativity

A

Electrons closer to the nucleus are more strong,y attracted towards its positive pull. So an increased atomic radius results in a decreased electronegativity

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4
Q

How does shielding affect the electronegativity

A

An increased number of inner shells and sub shells will result in a decreased electronegativity

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5
Q

What happens to electronegativity across a period/ down a group

A

It increases across across a period and decreases down a group

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6
Q

Definition of polarity

A

Is a covalent bond in which there is a separation of charge between one end and the other

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7
Q

How will a bond be non polar

A

When 2 atoms in a covalent bond have the same electronegativity the covalent bond is non polar

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8
Q

What’s is dipole moment

A

It is the measure of how polar a bond is

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9
Q

Definition of intermolecular forces

A

Are weak interactions between dipoles of different molecules

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10
Q

The 3 types of intermolecular forces are

A

Induced dipole dipole( London forces)- in everything
Permanent dipole dipole- between polar bonds ( opposite ends of molecules)
Hydrogen bonding- type of pd-d ( usually between H and N,O,F

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11
Q

Metallic bonding definition

A

The strong electrostatic force of attraction between the positively charged metal ions and the delocalised electrons

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12
Q

Ionic bonding definition

A

The strong electrostatic force of attraction between oppositely charged ions

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13
Q

Covalent bonding definition

A

The strong electrostatic force of attraction between a negative shared pair of electrons and the positive nucleus of the bonded atom

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14
Q

Electrons pair repulsion theory

A

The electrons on orbitals are negatively charged so they will repel each other so they will take position as far away from each other as possible to minimise repulsion

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15
Q

3 bonding pairs = what shape

A

Trigonal planar shape

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16
Q

4 bonding pairs

A

Tetrahedral

17
Q

5 bonding pairs

A

Trigonal bipyramidal

18
Q

6 bonding pairs

A

Octahedral shape

19
Q

Linear bond angle

A

180

20
Q

Trigonal planar bond angle

A

120

21
Q

Tetrahedral bond angle

A

109.5

22
Q

Trigonal bipyramidal bond angle

A

90 and 120

23
Q

Octahedral bond angle

A

90

24
Q

What happens with a lone pair is added

A

The bond angle reduces by 2.5degrees

25
Q

3 bonding pairs and a lone pair

A

pyramidal