electronegativity Flashcards

1
Q

def.

A

the relative power of an atom to attract the shared pair of electrons in a covalent bond

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2
Q

trends

A

increasing across periodsdecreasing down groups

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3
Q

why does it increase across periods

A

nuclear charge increases, shielding stays the same and atomic radius decreases

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4
Q

why does it decrease down groups

A

nuclear charge increases, BUT shielding increases and atomic radius increases.

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5
Q

what is a polar covalent bond

A

a polar covalent bond arises when electron density is not equally shared, therefore shared pair of electrons not equally shared, therefore partial charges arise

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6
Q

when do polar bonds also arise

A

when there is a difference win electronegativity between fused atoms

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7
Q

Suggest why the electronegativity of the elements increases from lithium to fluorine.

A

More protons / bigger nuclear chargeSame or similar shielding / electrons in the same shell or principal energy level / atoms get smaller

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8
Q

Although phosphine molecules contain hydrogen atoms, there is no hydrogen bonding between phosphine PH3 molecules.Suggest an explanation for this.

A

Difference in electronegativity between P and H is too small

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