Electron Configuration of Atoms and Ions Flashcards
Daltons Atomic Theory
Elements are made of atoms
All atoms of elements are identical same size mass and chemical properties (isotopes).
Chemical reaction involve separation, combination and rearrangement of atoms
JJ Thompson
• Discovered electron 1st subatomic particle
• Used cathode ray tubes and knowledge of electromagnetic theory to determine ratio of charge to mass of an electron
• -1.76 x 108C/g C = Coulomb the unit of electric charge
• Proposed the Plum Pudding model electrons embedded in uniformly positively charged sphere
• Most matter is neutral
Must positive bit to counteract the -ive charge in protons
Rutherford
- Nucleus was born when investigating plum pudding model
- Bombarded thin gold foil with alpha particles
- Most went through but some went straight back or were deflected
- Concluded that most of it was empty space and there was a dense positive core called the nucleus
Niehls Bohr
Electrons move in circular orbits
De Broglie
Particles can move in a wave like motion if Einstein is correct e.g electrons
Wave particle duality
Einstein
Light is a wave with particle properties
Heisenberg
The more precisely the precision of the position is determined the less precisely the momentum is known
Impossible to know the exact position and momentum of an electron at the same time
Called the Uncertainty Principle
Schrodinger Wave Equation
Probability of finding an electron within a particular position within an atom
Atomic Orbitals
Understand how atoms react with each other and predict how atoms might interact with each other
Defined as a region in space within the atom around the nucleus where the probability of finding an electron is rel. high
Electron Configuration
Different shape s orbital, (circle) varies within the principle quantum number.
P orbitals dumbbell shaped come in 3 px, py, pz same energy (degenerate)
D orbitals need to be able to draw it in a set of five dxy, dxz, dyz, dz2, dz2y2
Energy sublevel
A sublevel within a primary energy level
A group of atomic orbitals within an atom if which have the same energy
Pauli Exclusion
no more than 2 electron with opposite spin within an orbital
Aufbau Principle
lowest available energy is occupied first
Hunds Rule
orbitals of same energy filled individuality 1st then in pairs