Electron Configuration Flashcards

1
Q

period

A

row of periodic table

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2
Q

What does the period number correspond to?

A

principle energy level

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3
Q

group

A

column of periodic table

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4
Q

What does the group number correspond to?

A

number of electrons in valence level

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5
Q

What is electron configuration based on?

A

Quantum Mechanical Model

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6
Q

What will electrons in the ground state occupy?

A

lowest possible energy level

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7
Q

What can electrons only have?

A

specific energy levels

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8
Q

What is each energy level split into?

A

sublevels

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9
Q

Are all sublevels available at every energy level?

A

no

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10
Q

What are sublevel made up of?

A

a number of possible orbitals

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11
Q

What does each orbial have?

A

identical energy

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12
Q

How many possible orbitals does the s sublevel have?

A

1

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13
Q

How many possible orbitals does the p sublevel have?

A

3

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14
Q

How many possible orbitals does the d sublevel have?

A

5

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15
Q

How many possible orbitals does the f sublevel have?

A

7

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16
Q

What does each orbital represent?

A

a region in space with 90% chance of finding a specific electron

17
Q

How many electrons can occupy any specific orbital?

A

maximum 2 electrons

18
Q

Describe the s sublevel.

A

1 orbital

spherical

19
Q

Desribe the p sublevel.

A

3 orbitals

dumbell shaped

20
Q

Aufbau principle

A

gives order of electron configuration

21
Q

Hund Rule

A

gives half fill identical orbitals then pair up electrons

22
Q

Pauli Exclusion

A

no 2 electrons can be identical

23
Q

What must be done when drawing energy level diagrams for 3d and 4s?

A

Put overlap

24
Q

1st ionization energy

A

energy needed to remove 1 mol of electrons from 1 mol of atoms in gaseous state

removal of electron in highest energy level to infinity

25
How can first ionization energy be calculated?
from wavelength or frequency of convergence limit
26
successive energy level
energy needed to remove next mol of electrons then next and next
27
What does the energy needed to remove specific electron depend on?
nuclear charge (higher charge, more attraction to nucleus) distance from nucleus (further away, less attraction) shielding (full sublevels shild outermost electron, less attraction)
28
What are the two exceptions to the Aufbau Principle?
Cr [Ar] 4s1 3d5 Cu [Ar] 4s1 3d10 because s electron moves to d sublevel more stable
29
What does the energy of photon correspond to?
first ionization energy
30
uncertainty principle
cannot know where an electron is at any given moment in time but can work out where electron likely to be
31
atomic orbital
region around an atomic nucleus with a 90% probability of finding an electron
32
Why can electrons occupy same region of space despite mutual repulsion?
spin in opposite directions
33
Why do chromium and copper have different electron configurations?
half-full (or full) d sublevel relatively stable because minimizes electron repulsion with six singly occupied orbitals (or all orbitals filled)
34
What is the equation for the first ionization energy of hydrogen?
H(g) -\> H+ + e-