Electromagnetic radiation and atomic spectra Flashcards
What is the electromagnetic spectrum in order of highest to lowest energy and decreasing wavelength
gamma rays, X-rays, ultraviolet radiation, visible light, infrared radiation, and radio waves
Microwaves (like the ones used in microwave ovens) are a subsection of the radio wave
All electromagnetic radiation travels at the same what?
Velocity
What is wavelength and what is it measured in?
It is the distance between adjacent crests (or troughs) and is measured in nanometres 1 nm = 10‑9 m
What is frequency and what is it measured in?
It is the number of wavelengths that pass a fixed point in one unit of time, usually one second
Hz or s‑1
What happens if we increase the frequency in the equation
c=f×λ
the wavelength decreases
How to create a continuous spectrum
When a beam of white light is passed through a prism or from a diffraction grating onto a screen
What shows up as dark lines on the continuous spectrum on an absorption spectrum
If a beam of continuous radiation like white light is directed through a gaseous sample of an element, the radiation that emerges has certain wavelengths missing.
Explain what an emission spectrum is
an emission spectrum of a sample is produced by measuring the intensity of light emitted at different wavelengths;
photons of light energy are absorbed by atoms when electrons move from a lower energy level to a higher one;
Explain absorption spectra
atomic emission spectra are made up of lines at discrete frequencies;
in emission spectroscopy, high temperatures are used to excite the electrons within atoms - as the electrons drop to lower energy level, photons are emitted;
What is a photon?
a photon carries quantised energy proportional to the frequency of the radiation
absorption or emission of electromagnetic radiation causes it to behave more like what?
a stream of particles called photons
How to create an absorption spectrum
an absorption spectrum is produced by measuring how the intensity of absorbed light varies with wavelength
atomic emission spectroscopy and atomic absorption spectroscopy are used to identify and quantify what?
atomic emission spectroscopy and atomic absorption spectroscopy are used to identify and quantify the elements present in a sample
the concentration of an element within a sample is related to what?
the intensity of light emitted or absorbed