Chemical Equilibrium Flashcards
What does k represent?
The value of an equilibrium constant indicates the position of equilibrium
What have a value of 1 in equilibrium expression
The concentrations of pure solids and pure liquids
What is k dependent and independent of?
dependent of temperature
independent of concentration and pressure
For endothermic reactions, a rise in temperature causes?
an increase in k and the yield of the product is increased
For exothermic reactions, a rise in temperature causes?
a decrease in k and the yield of the product is decreased
Water equilibrium?
H2O + H20 arrow OH- + H30+
Word to describe water?
amphoteric
The dissociation constant?
Kw
At 25°C the value of Kw is approximately?:
1 × 10-14
The Brønsted-Lowry definitions of acids and bases state?
an acid is a proton donor and
a base is a proton acceptor
What is a strong acids and strong bases?
completely dissociated into ions in aqueous solution
What is weak acids and weak bases?
only partially dissociated into ions in aqueous solution
Examples of strong acids include?
hydrochloric acid, sulfuric acid and nitric acid
Examples of weak acids?
Ethanoic acid, carbonic acid and sulfurous acid
Strong bases?
Solutions of metal hydroxides
Example of weak bases?
Ammonia and amines
acid dissociation constant?
Ka
A soluble salt of a strong acid and a strong base dissolves in water to produce?
a neutral solution
The first part of the name of a salt identifies? The second part of the name of a salt identifies?
alkali/base was used to make the salt and the acid used to make the salt respectively
A buffer contains what?
a weak acid/base and a salt
acid indicator dissociation constant?
kin
the colour of an acid indicator is distinctly different from?
conjugate base
The colour of the indicator is determined by?
the ratio [Hin] to [In-]
The theoretical point at which colour change occurs is when?
[H30+] = kin
The colour change is assumed to be distinguishable when?
[Hin] and [In-] differ by a factor ten
The pH range over which a colour change occurs can be estimated by the expression
pH= pkin +/- 1