Atomic orbitals, electronic configurations and the periodic table Flashcards
Principal quantum number, symbol n, determines what?
the main energy level and it can have values n = 1, 2, 3, 4, etc. The numbers determine the size and energy of the shell.
Angular momentum quantum number, symbol ℓ, determines what?
the shape of the sub-shell and is labelled as s, p, d, f. This can have values from zero to ( n -1).
value 0 labelled as ‘s’ subshell;
value 1 labelled as ‘p’ subshell;
value 2 labelled as ‘d’ subshell;
value 3 labelled as ‘f’ subshell.
Magnetic quantum number (also known as magnetic quantum number), symbol mℓ, relates to what?
the orientation in space of the orbital eg if ℓ = 2 (labelled as a ‘d’ orbital)
mℓ could have the value +2, +1, 0, -1, -2
Spin magnetic quantum number: determines what?
the direction of spin. It is therefore called the spin quantum number, ms. It has values of +12 or −12
the aufbau principle
electrons fill orbitals in order of increasing energy
Hund’s rule
when degenerate orbitals are available, electrons fill each singly,
keeping their spins parallel before spin pairing starts
Pauli exclusion principle
no two electrons in one atom can have the same set of
four quantum numbers, therefore, no orbital can hold more than two electrons and
these two electrons must have opposite spins
what is a dative covalent bond?
atoms can provide pair of non bonding electrons that form the covalent bond