electrolysis of aqueous solutions Flashcards

1
Q

what depends on the relative reactivity of the elements involved?

A

The ions discharged when an aqueous solution is electrolysed using inert electrodes

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2
Q

what is the water in a solution broken down into + by?

A

electricity into hydrogen ions (H + )
and hydroxide ions (OH - ).

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3
Q

what is produced at the negative electrode (cathode)?

A

hydrogen is produced if the metal is more reactive than hydrogen.

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4
Q

what is produced at positive electrode?

A

oxygen is produced unless the solution contains halide ions
in which case the halogen is produced.

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5
Q

what happens in the electrolysis of a salt solution (brine)?

A

hydrogen is produced at the cathode,
chlorine is produced at the anode and sodium hydroxide solution is also formed.

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6
Q

what happens at the cathode?

A

positively charged ions gain electrons and so this is known as reduction.

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7
Q

what happens at the anode?

A

negatively charged ions lose electrons and so these reactions are
oxidations.

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8
Q

how can reactions at electrodes be represented?

A

by half equations, e.g.
2H + + 2e - H 2

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