Electrolysis Flashcards

1
Q

What is electrolysis

A

Electrolysis is a process in which electrical energy, from a direct current (dc) supply, decomposes (breaks down) electrolytes.
The free ions in electrolytes are attracted to the oppositely-charged electrodes connected to the dc supply.

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2
Q

What happens during electrolysis

A

negative ions are discharged at the positive electrode (anode)
positive ions are discharged at the negative electrode (cathode).

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3
Q

what is an electrolyte

A

the liquid that the electric current flows through

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4
Q

What is a cathode

A

a negative electrode where the positive ions (cations) are discharged

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5
Q

What is an anode

A

a positive electrode where the negative ions (anions) are discharged

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6
Q

What is a dc

A

Direct current

The power supply running through the electrolyte

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7
Q

Give some examples of cations (that would discharge at the cathode)

A

Hydrogen (H+)
Ammonium (NH4+)
Sodium (Na+)
Copper(II) (Cu2+)

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8
Q

Give some examples of anions (that would discharge at the anode)

A

Chloride (Cl-)
Oxide (O2-)
Hydroxide (OH-)
Sulfate (SO42-)

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9
Q

What happens when ions reach an electrode

A

They gain or lose electrons. As a result, they form atoms or molecules of elements

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10
Q

What happens cations reach the cathode

A

They gain electrons from the negatively charged cathode

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11
Q

What happens when and ions reach the anode

A

They lose electrons that the positively charged anode

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12
Q

What happens during the electrolysis of molten salts

A

A metal bones at the cathode and a non-metal forms at the anode

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13
Q

What happens during the electrolysis of acidified water

A

H+ ions are attracted to the cathode, gain electrons form hydrogen gas
OH- ions are attracted to the anode, lose electrons and form oxygen gas
(2H20 —— 2H2 + O2)

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14
Q

What happens during the electrolysis of dissolved ionic compounds

A

The electrolyte contains…
🏮Hydrogen ions from the water and positive ions from the compound
🏮Hydroxide ions from the water and negative ions from the compound

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15
Q

What determines whether hydrogen or a metal will be produced at the cathode

A

Position of the metal in the metal reactivity series…
🏮The metal will be produced if the metal is less reactive than hydrogen.
🏮Hydrogen will be produced if the metal is more reactive than hydrogen

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16
Q

List the reactivity series so most reactive to least reactive

A
Potassium
Sodium
Lithium
Calcium
Magnesium
Aluminium 
Carbon
Zinc
Iron
Hydrogen
Copper
Silver
Gold