electrolysis Flashcards

1
Q

why cant sold ionic compounds conduct electricity

A

the ions are locked and cant move

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2
Q

how can ionic compounds conduct electricity and why

A

though being melted or dissolved in water
the forces of attraction are broken so ions are free to move and conduct elect

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3
Q

what are ionic compounds that can conduct elec called

A

electrolytes

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4
Q

what is the negative electrode

A

cathode

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5
Q

what is the postive electrode

A

anode

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6
Q

what is the cathode attracted to

A

protons

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7
Q

what is anode attracted to

A

electrons

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8
Q

what is high in aluminium oxide
Al2O3

A

its melting point approx 2000^c

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9
Q

what is Al2O3 mixed with and why

A

with creolite to lower melting point
reducing energy and energy costs

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10
Q

in Al2O3 what are the electrodes made of

A

graphite (carbon)

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11
Q

in Al2O3 the ions are..

A

ions are free to move

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12
Q

what is Al+3 attracted to and the type of reaction

A

cathode
reduction

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13
Q

what is the half equation for Al+3

A

Al+3 + 3e- —> Al

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14
Q

what is O2- attracted to and the type of reaction

A

anode
oxidation

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15
Q

what is O2-‘s half equation

A

2o2-4e—>o2

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16
Q

why does the anode have to be replaced regularly

A

the oxygen molecules react with the graphite to form co2 which damages it

17
Q

why is electrolysis of Al2O3 expensive

A

melting compounds require lots of energy and lots of energy required to produce electric current

18
Q

what happens with electrolysis of aqueous solutions and equation

A

water molecules ionise to form hydrogen ions and hydroxide ions
H2O —-(rvrs) H+ + OH-

19
Q

what ions are formed with CuSO4 (aq)

A

Cu2+/H+ and SO4.2-/OH-

20
Q

what happens when the metal element is more reactive than hydrogen in aq

A

then hydrogen will be produced at the cathode

21
Q

what happens when the metal element is less reactive than hydrogen in aq

A

then the said element is produced at the cathode

22
Q

for CuSO4 what is used as an inert electrode

A

platinum

23
Q

what is produced at the anode for CuSO4

A

4OH- —-> O2 + 2H2O + 4e-
ox

24
Q

for CuSO4 what is produced at cathode

A

Cu2+ + 2e- —> Cu
reduc

25
Q

what happens if the aq solution contains halide ions

A

halogen is produced at the anode