electrolysis Flashcards

1
Q

what is meant by electrolysis

A

the breakdown of substances (electrolyte) using electricity

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2
Q

why are the electrodes usually inert/ unreactive

A

so they dont react w the elctrolysis product or the electrolyte

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3
Q

why can ionic compounds only be electrolysed when theyre molten or dissolved in water

A

cause their ions are free to move around and carry diff chargers to the eletrode

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4
Q

whats the charge of an anode

A

positive electrode

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5
Q

whats an cathode

A

negative electrode

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6
Q

what happens at the cathode

A

positively charged ions gain electrons to become stable elements

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7
Q

what happens at the anode

A

negitvely charged ions loose electrons to become stable elements

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8
Q

how can reactions at the electrodes be represented

A

half equations

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9
Q

what happens in electolysis of aqeous solutions

A

in cathode-less reactuve element (metal or hydrogen) is displaced and the more reactive one is left in the solution
in anode- hydroxide ions are discharged unless a halide ion is pressent

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10
Q

whatre the steps of extracying aluminium

A

baxuxite is purified -> aluminium oxide is electrolysed to form aluminium and oxygen

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11
Q

whatre the steps to electrolyse aluminium oxide

A

1- molten aluminium oxide is mixed with cryolite to lower its melting point so less energy is needed
2- carbon electrodes need to be regularly replaced or they burn away
3-aluminium is formed in the cathode and oxygen formed in anode

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12
Q

what happens in the anode and cathode in the elctrolysis of aluminium oxide

A

cathode- aluminium is reduced (gains 3 electrons)
to form Al atoms
anode- oxygen is oxidised (loses 2 electrons) then reacts with the carbon anode to form carbon dioxide gas

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13
Q

What is the name of the substance that is mixed with aluminium oxide to lower its melting point?

A

cryolite

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14
Q

whatre the 3 products you get from electrolysising concentrated sodium chloride (brine)

A

sodium hydroxide,chlorine and hydrogen

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15
Q

what happens in the anode cathode and rest of solution in brine

A

anode- chlorine is oxidised (loses an electron)
cathode- hydrogen displaces sodium and is reduced to (gains 2 electrons)
sodium and hydroxide ions left in the solution react to form sodium hydroxide

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16
Q

whatre the uses of hydrogen,chlorine and sodium hydroxide

A

hydrogen can be used to make margirine
sodium hydroxide used to make paper and bleach and soap
chlorine used to make bleack to disinfect bacteria and plastics

17
Q

where are metals usually formed

A

at the cathode

18
Q

whats meant by electroplating

A

coating an object with a metal layer by electrolysis

19
Q

why do we electroplate

A
  • to protect metal from scratches nd corroding
  • to preserve and use less amts of expensive and rare metals
  • to increase attractiveness
20
Q

how do we electroplate

A
  • use plated object at cathode
    -use plating metal as anode
    -use ions of plating metal in electrolyte
21
Q

what happens when you electolyse copper sulfate

A

-the cathode gains mass (metals formed) and the anode loses the same mass the cathode gains

22
Q

loss of mass in anode when using active electrode =..

A

gain of mass in cathode

23
Q

what happens when carbon electrodes are used in copper sulfate

A

copper is still deposited at cathode
oxygen is given off in anode from the hydroxide ions in electolyte