Electrochemistry Flashcards

1
Q

Cathode

A

the SOA and site of reduction half reaction

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2
Q

Anode

A

the SRA and site of oxidation half reaction

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3
Q

Electrode

A

solid pieces of metal where half reactions occur

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4
Q

Salt bridge

A

allows the flow of ions between half cells

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5
Q

Flow towards the anode

A

Anions

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6
Q

Flow towards the cathode

A

Cations

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7
Q

(Type of cell) are spontaneous

A

Volatic cells

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8
Q

(Type of cell) are not spontaneous

A

Electrolytic cells

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9
Q

Wire

A

allows electrons to flow from anode to cathode

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10
Q

An SOA half reaction represents the..

A

cathode

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11
Q

An SRA half reaction represents the..

A

anode

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12
Q

Electrons flow from..

A

anode to cathode

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13
Q

Anions move to the anode from the…

A

cathode half cell

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14
Q

Cations move to the cathode from the…

A

anode half cell

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15
Q

Inert electrode

A

an electrode (solid metal) that doesn’t react

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16
Q

Common inert electrodes

A

Carbon (C) or platinum (Pt)

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17
Q

When must an inert electrode be used?

A

when there is not a solid in the half reaction

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18
Q

Any half reaction higher than hydrogen (0) has…

A

a positive potential difference

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19
Q

Any half reaction lower than hydrogen (0) has…

A

a negative potential difference

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20
Q

Potential difference (voltage) formula

A

cathode - anode or SOA - SRA

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21
Q

If the reduction potential for Ag+ is +0.80, then what is it’s oxidation potential?

A

-0.80

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22
Q

Converts chemical energy to electrical energy

A

Voltaic cells

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23
Q

Converts electrical energy to chemical energy

A

Electrolytic cells

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24
Q

E net is positive

A

Voltaic

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25
E net is negative
Electrolytic
26
Ex. of what? Ag (s)|AgNO3 (aq)||Zn(NO3)2 (aq)|Zn (s)
Voltaic cell
27
Ex. of what? C (s)|CuSO4 (aq)|C (s)
Electrolytic cell
28
What type of cell needs two seperate beakers for an experiment?
Voltaic cells
29
What type of cell can use one whole beaker for an experiment?
Electrolytic cells
30
What does it mean when a substance is molten?
no water is present
31
How do you determine a molten substance?
if an ionic compound has a liquid subscript (l)
32
Formula to find moles of electrons
Ne=IT/F
33
Ne = ?
moles of electrons
34
I = ?
current (amps) c/s
35
T = ?
time (seconds)
36
F = ?
faraday's constant
37
What words help determine if a question is cell stoich?
plated, current, or time
38
Dry cell
sealed electric cell with semi-solid conductors
39
Primary battery
cell that can't be recharged
40
Secondary battery
rechargeable cell
41
Fuel cell
cell where the fuel is continuously added
42
Disporportionation reaction
occurs when a substance is both the OA and RA
43
What reaction types are redox reactions?
single rep., formation, decomposition, combustion
44
What reaction types are not redox reactions?
dbl rep., dissociation
45
What is the oxidation number for all pure elements?
0
46
What is the oxidation number for oxygen and what is the one exception?
it is always -2, except in peroxides which then it is -1
47
What is the oxidation number for groups 1 and 2 on the periodic table?
group 1 is +1, group 2 is +2
48
How is the oxidation number determined when two nonmetals combine?
the one with the higher EN will be the starting point to determine the others
49
If the word "acidic" or "basic" is mentioned in a question, what species should be listed?
H+ and OH-
50
What type of acids are not ionized meaning they don't dissociate completely?
weak acids
51
What type of acids are ionized meaning they dissociate completely?
strong acids
52
Reduction
gaining electrons
53
Oxidation
losing electrons
54
Ingredient added that causes reduction
RA
55
Ingredient added that causes oxidation
OA
56
Get oxidized, not reduced
RA's
57
Get reduced, not oxidized
OA's
58
Gain electrons, get reduced
OA's
59
Lose electrons, get oxidized
RA's
60
When electrons are lost, they are on...
the right side of the equation
61
Electrons on the right side of equation
oxidation
62
When electrons are gained, they are on...
the left side of the equation
63
Electrons on the left side of the equation
reduction
64
What happens to the electrons and overall charge when oxidation occurs?
electrons are lost, and charge gets more positive
65
What happens to the electrons and overall charge when reduction occurs?
electrons are gained, and charge gets more negative