Dry Etch Flashcards
Etch rate can:
- vary across a substrate
- can change with etch depth
- can vary with etch direction
Mean free path is:
The average distance travelled by a particle between interactions with other particles. It is dependent on pressure, particle diameter and temperature
What are four types of dry etching?
1) Sputtering (directional etch)
2) Chemical (isotropic etch)
3) Ion-enhanced energetic (vertical etch)
4) Ion-enhanced inhibitor (vertical etch)
Isotropic etching is
The same in all directions
Sputtering (Ion milling) uses
high energy ions to bombard the material and do ballistic damage
What are the benefits and disadvantages of sputtering?
Benefits: mechanical, not chemical so it can etch almost any material
Disadvantages:
- slow
- causes crystal damage
- poor selectivity
- requires higher vacuum
What are the benefits and disadvantages or chemical plasma etch processes?
Benefits:
- can achieve excellent material selectivity
- Isotropic or weakly anisotropic
Disadvantages
- isotropic
- loading induced anisotropy
Vapor phase etching benefits and disadvantages
Benefits:
- Chemical not mechanical, can achieve excellent selectivity
- Isotropic or anisotropic
- Inexpensive
- doesnt require plasma
Disadvantages
- loading induced anisotropy
- dangerous gaseous byproducts such as HF
Reactive Ion etching uses
Both plasma and vapor phase etching, by accelerating reactive species in a plasma towards a substrate. Crystalline / mechanical damage associated with the ion bombardment enhances the chemical etching.
- Mixtures of gasses are often used to simultaneously etch and passivate (increases anisotropy, by protecting side walls with passivating compounds)
Deep reactive Ion Etching (DRIE)
Uses passivation to increase the anisotropy of the etching process, enables AR up to 30:1.
Cryogenic:
- cools substrate, etch products get stuck to substrate side walls improving passivation
- large thermal stresses
Bosch Process
- Repeated alternating etch and deposition steps
- Uses a deposited polymer to protect sidewalls while etching bottom with ion bombardment
Issues with DRIE
- side wall scalloping
- Rough side walls, potential for crack propagation
- high AR makes it stiff
- High AR etches very slowly