Diffusion Flashcards

1
Q

Diffusion equation

A

dP/dt = Dgrad^2(P)

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2
Q

What is diffusion

A

a kinetic process that leads to homogenization of a solution

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3
Q

Laplace operator

A

grad^2

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4
Q

covariance of noise

A

= 2Ddelta(ab)delta(t-t’)

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5
Q

brownian motion exact form and forces

A

m(d^2x/dt^2) = -(1/mu)(dx/dt)-(dV/dx)+fr(t)

3 forces

1) friction force in low reynold number limit (mu = 6pi(specific viscosity)*R)^-1
2) force due to external potential V
3) random force (fr) due to particle impacts

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6
Q

brownian motion, simplified

A

usually overdamped

dx/dt = -v(x)+nu(t)

v = -mu*dV/dx
nu= mu*fr(t)
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7
Q

einstein relation for diffusion

A

D =kbTmu

mu = dynamic viscosity

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8
Q

markov process

A

random process where future is independent of past

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9
Q

markov chain

A

the future state only depends upon the current state (it’s a probability calculation

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10
Q

ergodic

A

will reach all points in the system

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11
Q

bayes theorem

A

P(A|B) = P(B|A)*P(A)/P(B)

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12
Q

basic def of a random walk

A

can travel in all directions with equal probability

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