Diffusion Flashcards
Diffusion equation
dP/dt = Dgrad^2(P)
What is diffusion
a kinetic process that leads to homogenization of a solution
Laplace operator
grad^2
covariance of noise
= 2Ddelta(ab)delta(t-t’)
brownian motion exact form and forces
m(d^2x/dt^2) = -(1/mu)(dx/dt)-(dV/dx)+fr(t)
3 forces
1) friction force in low reynold number limit (mu = 6pi(specific viscosity)*R)^-1
2) force due to external potential V
3) random force (fr) due to particle impacts
brownian motion, simplified
usually overdamped
dx/dt = -v(x)+nu(t)
v = -mu*dV/dx nu= mu*fr(t)
einstein relation for diffusion
D =kbTmu
mu = dynamic viscosity
markov process
random process where future is independent of past
markov chain
the future state only depends upon the current state (it’s a probability calculation
ergodic
will reach all points in the system
bayes theorem
P(A|B) = P(B|A)*P(A)/P(B)
basic def of a random walk
can travel in all directions with equal probability