DF1/DF2 (Enthalpy Changes & Hesse’s law) Flashcards
is bond breaking endothermic?
yes
what is bond making?
exothermic
what is the enthalpy change for an exothermic and endothermic reaction?
exo is negative, endo is positive
what is the equation for enthalpy change?
energy of the products - energy of the reactants
why is delta H negative for exothermic reactions?
because energy has been lost from the chemical bonds to the surroundings
what are the 3 standard conditions for enthalpy?
standard temperature 298K
100kPa
1M concentration
how do you convert kelvin to celsius and vice versa?
celsius to kelvin, add 273
kelvin to celsius, minus 273
what is the standard enthalpy change for a reaction?
the enthalpy change when molar quantities of reactants react together under standard conditions
what is the standard enthalpy change of combustion?
when one mole of a substance is burnt completely in oxygen
what is the standard enthalpy change for formation?
enthalpy change that occurs when one mole of a compound is formed from its elements
what is standard enthalpy change of neutralisation?
enthalpy change that can be measured from the energy given out when acids react with alkalis in aqueous solutions.
how do you use Hesse’s law to draw enthalpy cycles?
write the equation you’re trying to find at the top of the cycle
look at the given data
look at the third elements/compounds in the triangle
make the triangle
work out how to calculate deltaH1
add the values