Definitions Flashcards

1
Q

Mole

A

The amount of substance containing as many particles as there are carbon atoms in exactly 12g of carbon -12

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2
Q

Transition Element

A

A d-block element that forms an ion with an incomplete d-subshell
Transition element atoms lose their 4s electrons first when forming +ions (cations)

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3
Q

Atomic Orbital

A

Is a region within an atom, around the nucleus, that can hold up to two electrons, with opposite spins

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4
Q

Acid

A

A proton (H+) donor

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5
Q

Base

A

A proton (H*) acceptor

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6
Q

Atomic Number

A

Equal to number of protons in nucleus of an atom

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7
Q

Mass Number

A

Equal to the number of protons and neutrons in the nucleus of an atom

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8
Q

Isotopes

A

Atoms of the same element with different numbers of neutrons

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9
Q

Relative Atomic Mass(Ar)

A

The weighted mean mass of an atom of an element compared with 1/12 of the mass of an atom of carbon-12

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10
Q

Relative isotopic mass

A

The mass of an atom of an isotope compared with 1/12 of the mass of an atom of carbon-12

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11
Q

Alkali

A

A base that dissolved in water and releases OH- ions in aqueous solutions

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12
Q

Strong and Weak acid

A

S- completely dissociates into its ions in aqueous solutions

W- partially dissociates into its ions in aqueous solutions

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13
Q

Salt

A

A compound produced when the H+ ion of an acid is replaced by a metal ion or NH4+

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14
Q

Successive ionisation energies

A

Successive ionisation energies are a measure of the energy required to remove each electron in turn

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15
Q

First ionisation energy

A

The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions

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16
Q

Homologous series

A

A family of compounds containing the same functional group but with each successive member of the series differing by a -CH2 group

17
Q

Structural isomerism

A

Moles with the same molecular formula but different structural formulae

18
Q

Hydrocarbon

A

A compound that contains ONLY hydrogen and carbon atoms

19
Q

Functional group

A

An atom/group responsible for the characteristic reactions of the compound

20
Q

Aromatic compounds

A

Compounds containing a benzene ring

21
Q

Aliphatic compounds

A

Compounds of carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings

22
Q

Homolytic Fission

A

The breaking of a covalent bond where one electron from the bonding pair goes to each atom to form two radicals

23
Q

Heterolytic fission

A

The breaking of a covalent bond where one bonding atom receives both electrons from the bonding pairs to form two ions with opposite charges

24
Q

Alicyclic compounds

A

Arranged in non-aromatic rings with or without side chains

25
Exothermic reaction
a reaction where heat energy is released to the surroundings. The enthalpy change for the an exothermic reaction has a negative(-) sign Bond forming gives out energy=exo
26
endothermic reaction
A reaction where heat energy is absorbed from the surroundings the enthalpy change when an endothermic reaction has a positive(+) sign Bond breaking requires energy= endo
27
stereoisomers
compounds with the same structural formula but with a different arrangement of the atoms in space
28
electrophile
Electrophile is an electron pair acceptor
29
curly arrow
Arrow shows the movement of an electron pair to either break or make covalent bond
30
enthalpy change of neutralisation
enthalpy change that accompanies the formation of one mole of H2O from neutralisation under standard conditions
31
enthalpy change of formation
enthalpy change when one mole of a compound is formed from its elements under standard conditions
32
enthalpy change of combustion
enthalpy change for the complete combustion of one mole of a substance under standard conditions
33
Average bond enthalpy
The average enthalpy change for the breaking of one mole of bonds in gaseous molecules by homolytic fission
34
Dehydration of an alcohol
a reaction where a H2O molecule is removed from a saturated molecule to form an unsaturated molecule
35
Nucleophilic Substitution
CH3CH2OH + NaBr + H2SO4 ->CH3CH2Br NaHSO4 + H2O conditions: heat under reflux
36
nucleophile
electron pair donor