Deck 7 Flashcards
Hess’law
Hess’law states that, if a reaction can take place by more than one route and the initial and final conditions are the same, the total enthlpy change is the same for each route.
An enthalpy cycle
Is a diagram showing alternative routes between reactants and products which allows the indirect determination of an enthalpy change from other known enthalpy changes using Hess’law.
The rate of reaction
The rate of reaction is the change in concentration of a reactant or a product in a given time.
Heterogeneous catalysis
Is catalysis of a reaction in which the catalyst has a different physical state from the reactants; frequently, reactants are gases whilst the catalyst is a solid.
Homogeneous catalysis
Homogeneous catalysis is catalysis of a reaction in which the catalyst and reactants are in the same physical state, which is most frequently the aqueous or gaseous state.
The Boltzmann distribution
The Boltzmann distribution is the distribution of energies of molecules at a particular temperature, often shown as a graph.
le Chatelier’s principle
le Chatelier’s principle states that when a system in dynamic equilibrium is subjected to a change, the position of equilbirum will shift to minimise the change.
Dynamic equlibrium
Dynamic equilibrium is the equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction.
The greenhouse effect
The greenhouse effect is the process in which the absorption and subsequent emission of infrared radiation by atmoshperic gases warms the lower atmosphere and the planets surface.
The troposphere
The troposphere is the lowest layer of the Earth’s atmosphere, extending from the Earth’s surface up to about 7km (above the poles) and to about 20Km(above the tropics).
The stratosphere
The stratosphere is the second layer of the Earth’s atmosphere, containing the “ozoner layer”, about 10km to 50km above the Earth’s surface.
Adsorption
Adsorption is the process that occurs when a gas, liquid or solute is held to the surface of a solid or, more rarely, a liquid.