Deck 5 Flashcards
Volatility
Volatility is the ease that a liquid turns into a gas. Volatility increases as boiling point decreases.
Reflux
Reflux is the continual boiling and condnesing of a reaction mixture to ensure that the reaction takes place without contents of the flask boiling dry.
Esterification
Esterification is the reaction of an alcohol with a carboxylic acid to produce an ester and water.
Dehydration
Dehydration is an elimination reaction in which water is removed from a saturated molecule to make an unsaturated molecule.
Hydrolysis
Hydrolysis is a reaction with water or aqueous hydroxide ions that breaks a chemical compound into two compounds.
Nucleophilic substitution
Nucleophilic substitution is a type of substitution reaction in which a nucleophile is attracted to an electron-deficient centre or atom, where it donates a pair of electrons to form a new covalent bond.
A limiting reagent
A limiting reagent is the substance in a chemical reaction that runs out first.
%yield=
actual amount,in mol, of product / theoretical amount,in mol, of product x 100
atom economy=
molecular mass of the desired product/ sum of molecular masses of all products x 100
Molecular ion
Molecular ion is the positive ion formed in mass spectrometry when a molecular loses an electron.
Fragmentation
Fragmentation is the process in mass spectrometry that causes a positive ion to split into pieces, one of which is a positive fragment ion.
A radical
A radical is a species with an unpaired electron
An electrophile
An electrophile is an electron pair acceptor.
A nucleophile
A nucleophile is an electron pair donor.