D1: Vinification - from PS Hill Flashcards
What are the compounds that make up wine?
Water is about 85%
Alcohol
Glycerol
Acids - tartaric and malic, smaller amounts of lactic and acetic
Wine aromatics
Residual sugar
Phenolics
What compounds can add sweetness, or a sweet sensation, to a wine?
Residual sugar
Alcohol can contribute a sense of sweetness
Glycerol has a slightly sweet taste
What impact does alcohol have on the taste of wine?
Adds a sense of sweetness and bitterness.
Warms the mouth
Gives the wine body
May reduce the volatility of aromas
What is a typical wine pH?
3-4 (3 is 10 x more acidic that 4)
What is the typical unit of measure of acid in a wine and what range is normal?
Equivalent g/l of tartaric acid - normally 5.5 - 8.5 g/l
What acid is considered a fault in high concentration?
Acetic acid (vinegar)
Give 2 examples of grape derived aromatic compounds
Methoxypyrazines - grassy/green pepper in Sauvignon Blanc
Rotundone - pepper aroma in Shiraz/ Grüner Veltliner
What is 4MMP?
Aromatic compound released in fermentation that gives box tree aroma to Sauvignon Blanc
What are terpenes? Give examples
Aroma compounds formed from precursors during fermentation
From Muscat:
Linalool (floral)
Geraniol (rose like)
How are esters derived?
Esters are formed from acid and alcohol, during fermentation
What do esters contribute to a wine?
Fresh and fruity flavours in young wine - e.g. apple/ pineapple
e.g. isoamyl acetate gives aroma of bananas
What aroma compounds originate from fermentation?
Esters (fruity, sweet flavours)
Acetaldehydes (fino sherry)
Diacetyl (buttery aroma)
Sulphurous compounds (struck match to rotten eggs)
Give 2 examples of aroma compounds that are not grape or fermentation derived
Vanillin comes from oak
Eucalyptol can be absorbed into grape skins from nearby eucalyptus
Name a model for categorising wine aromas, and the key categories that make it up
Vicente Ferreira’s model for wine aromas
- compounds common to all wine
- impact aromas
- contributory aromas
- nonvolatile wine matrix
What range of residual sugar might you fine in different wines?
‘Brut nature’ sparkling - 0-1g/l
Dry wine: 2-3g/l
Port: 35-120 g/l
Sweet wine: Sauternes 150 g/l
Sweet wine: Perdo Ximenez 400 g/l
What are the EU classifications of sweetness in still wine?
Dry/sec/trocken: up to 4 g/l, or up to 9g/l if acid is not more than 2 g/l less
Medium dry/ demi-sec/ halbtrocken: 4-12 g/l, or up to 18 g/l if acid is not more than 10 g/l less
Medium sweet/ ioelleux/ lieblich: 12-45 g/l
Sweet: 45 g/l or more
Give examples of phenolic compounds
Anthocyanins
Tannins
What are common practices for making organic wine?
Depends on the certifying body. e.g. EU allows SO2 to be added, US excludes it.
Use organic raw materials where possible. e.g. organic egg white for fining
Excludes certain practices, e.g. partial dealcoholisation of wine
What are the sources of wine aromatic compounds?
- Aromas from grapes
- Aromas created from grape precursors
- Aromas created by fermentation
- Aromas from other sources
What are common practices for biodynamic winemaking?
Always made from certified biodynamically grown grapes
Other requirements can vary by county, even when certified by Demeter International.
e.g. UK producers can use organic or commercial yeast types. US can only use commercial year on a case by case basis, if fermentation is stuck
Adding many products is not permitted. e.g. isinglass
What are common practices for natural winemaking?
There is no agreed definition of a natural wine
Typically refers to the fewest possible interventions. e.g. use ambient yeast, minimal SO2.
What 2 gases are fundamental to the majority of winemaking?
Oxygen
Sulphur dioxide
What impact does the presence of oxygen have on wine?
Oxygen typically breaks down many flavours that make fresh, fruity wines. e.g. thiols in Sauvignon Blanc
Oxidation typically creates nutty/ savoury flavours, e.g. acetaldehyde
White wines become darker and browner
What compounds may help protect against the presence of oxygen in still wine?
Phenolic compounds in red wine are anti-oxidative
How are oxygen levels limited in winemaking?
Avoid ullage in vessels; fill to the top and use tight seals
Use inert gases to flush out oxygen/air from equipment before it makes contact with wine
Add sulphur dioxide, which is anti-oxidative
Use impermeable containers: stainless steel and concrete over wood; screw cap over cork
Keep temperatures lower
When is oxygen required in winemaking?
At the start of fermentation, oxygen promotes healthy yeast growth
Early exposure may increase the stability of white wine to oxygen increasing ageing potential
In red wine oxygen is required for the reactions between anthocyanins and tannins that stabilise colour
Some oxygen exposure derived compounds may give desired characteristics: dried fruits, honey, caramel, coffee, leather, mushrooms
Some fortified wine requires oxygen: Oloroso, Madeira, Tawny port
How is oxygen exposure increased during winemaking?
Cap management techniques that spray/splash wine
Smaller wooden barrels
increase rackings/ lees stirring
Increase ullage
pump oxygen through (micro-oxygenation
What properties does sulphur dioxide have in winemaking?
Anti-oxidant (indirect)
Anti-microbial
What SO2 levels are permitted by the EU?
160 mg/l in red wine
210 mg/l in white wine
Over 10 mg/l requires a label that the wine contains sulphites
How can winemakers reduce SO2 requirements?
Good hygiene and grape sorting limit microbes
Limiting oxygen exposure during winemaking
Lower temperatures during winemaking
What states does SO2 exist in wine and how can these be influenced?
Bound SO2 has reacted with compounds in the wine and has limited benefits
Free SO2 is either inactive (most) or molecular (limited proportion).
Molecular SO2 is most beneficial.
Greater proportions exist at lower pH
How are grapes and must protected in harvest and transportation?
Pack in smaller crates to protect against crushing
Keep temperatures lower - harvest at night
Add SO2 (potassium metabisulfite)
Keep equipment clean/ sanitised
What processes may a grape be exposed to before fermentation?
Chilling
Sorting, or triage
Destemming
Crushing
How can grapes be sorted?
Remove unwanted grapes/bunches before harvest
Sort by hand - on a table, a conveyer belt, or a vibrating belt (also removed MOG)
Optical sorting
What are the implications of increasing sorting?
Increasing sorting, typically increases cost, and lowers yields as more grapes are removed. It may be required in poor years, if there are larger number of unripe or mouldy grapes
Why are some grapes not de-stemmed?
It depends on the wine being made:
- Some red wine fermentations use whole bunches, which increase tannin levels from stems (stems need to be ripe)
- carbonic maceration needs whole bunches
- some white wines and sparkling wines require whole bunch pressing
Explain crushing vs. pressing
Crushing breaks the skin of grapes and releases juice to instigate fermentation. Care is taken to leave seeds whole. Can be carried out by feet.
Pressing is the separation of juice or wine from skin and seeds
What are the common types of press?
Pneumatic press uses and air sack in a tank to apply pressure to grapes. Investment is greater, but the pressure control is greater and inert gas flushing can be carried out.
Basket press (also vertical or Champagne press) is unsealed, possibly more gentle that a pneumatic press, but more labour intensive as they hold a smaller load
Horizontal screw press is similar to a basket press
Continuous presses, which are better suited to high volume, inexpensive wine
What is the name for solid remains left over pressing?
Pomace
What are the common adjustments made to must?
Enrichment (chaptalisation, concentration, RCGM addition)
Reducing alcohol (dilution)
Acidification (4 types of acid commonly added: Tartaric, malic, citric, lactic)
Deacidification (2 compounds commonly added: potassium carbonate, calcium carbonate)
What practices are covered by the term ‘enrichment’?
Chaptalisation - adding dry sugar
Concentration of sugar levels. e.g. reverse osmosis/ cryoextraction
Adding RCGM or other grape products
What level of chaptalisation is allowed in the EU?
It depends on the area:
Cooler regions may add up to 3% (to a maximum of 11.5% in white and 12% in red)
Warmer regions may add up to 1.5%, and are limited to grape concentrate or RCGM
How is alcohol reduced prior to fermentation?
Typically dilution with water, although the practice is tightly controlled. Aromas and flavours are also diluted
How and when is acidification carried out?
Tartaric acid is usually added, although citric (not in the EU), malic and lactic acids can also be added
Acidification can happen at any point, although typically before fermentation
What level of de-/acidification is allowed in the EU?
It depends on the area:
In cooler climates, deacidification of up to -1 g/l is allowed
In warmer climates, acidification of up to 2.5 g/l is allowed
Why do winemakers acidify must/wine?
In warmer climates, malic acid levels may drop dramatically during ripening
How is deacidification carried out?
Calcium carbonate or potation carbonate is added, which precipitates tartrates out of the must/wine
If deacidication is carried out prior to fermentation, the winemaker must bear in mind some further reduction in acid may take place due to MLF
What compounds are produced during fermentation?
Yeast primarily convert sugar into alcohol and carbon dioxide, in the absence of oxygen
Other compounds include:
- small amounts of volatile acid
- small amounts of SO2
- aromatics from aroma precursors (e.g. thiols like 4MMP)
- aromatics from yeast (e.g. esters that give fruity flavours)
Glycerol
What species of yeast are used by wine makers?
Saccharomyces cerevisiae is the most common due to its resistance to SO2 and alcohol levels
Saccharomyces bayanus is used for higher alcohol content, or re-fermenting sparkling wine
What yeast sources are there?
Ambient yeast - mixed yeast varieties that live on grapes and in the winery, although S. cerevisiae is dominant over 5% alcohol
Cultured yeast from a laboratory can be selected for different characteristics. e.g. enhancing aromatics, or retained fruit
List the advantages and disadvantages of ambient yeast for fermentation
Advantages:
- increased complexity of aroma compounds
- free
- unique varieties may lead to unique expressions of terroir
- marketing tool
Disadvantages:
- risk of spoilage yeasts (brettanomyces) and bacteria
- fermentation may take longer or get stuck
- variable product
List the advantages and disadvantages of cultured yeast for fermentation
Advantages:
- reliable, fast fermentation
- less danger of spoilage
- consistent product
- choice of strains to impact flavour
Disadvantages:
- cost
- potential similarity of flavours across the industry
What are typical fermentation temperature ranges for different wine styles?
Cool: 12–16°C for fresher fruitier white and rosé
Mid-range: 17–25°C for easy drinking red, or barrel fermented white
Warm: 26–32°C for powerful reds to maximise colour and tannin extraction
How is temperature controlled during fermentation?
Coolant jackets in stainless steel vats
Move ferments into warmer/cooler cellars
Pumping over (délestage) reduces heat
What are different fermentation vessels normally made from and what characters do they bring?
Stainless steel - neutral, good temperature control, good for mechanisation
Concrete - efficient temperature control. Can be cheap, or expensive. Lined with resin
Wood - need good hygiene. Retains heat. May oxygenate more. Less common for reds due to poor cap management
What is MLF and how does it arise?
Malolactic Fermentation, or conversion, is from lactic acid bacteria converting malic acid to lactic acid
Needs a temperature >15°C, a low pH and low-moderate SO2
Which wines typically go through MLF?
All red wine, in combination with normal fermentation, because of the higher temperatures of fermentation
Acidic white wines in non-aromatic grape varieties, e.g. Chardonnay
What characteristics does MLF bring to a wine?
Reduction in acidity
Some red colour loss
Greater microbial stability
Potential reduction of fruit character and addition of buttery flavour
What techniques can reduce alcohol post-fermentation?
Reverse osmosis to remove a mixture of water and alcohol - distillation can remove alcohol from this mix before adding it back
Equipment called a spinning cone
How can colour be adjusted?
Fining may reduce unwanted colour
Some colours may be added, e.g. grape derived MegaPurple
What are the main choices when storing wine before bottling?
Fruity, fresh wines that have limited oxygen exposure are likely to be held in stainless steel and bottled quickly after fermentation
Wine may be matured in bulk in large inert vessels, or barrels that allow slow oxygen exchange
Barrels may be old or new wood
Wine may be help on its lees, and stirred or left.
How does the role of oxygen impact the maturation of white wine differently to red wine?
Red wine has anti-oxidative properties from phenolic compounds. Therefore it can typically withstand a longer maturation of 12-24 months, compared with 6-12 for whites
How does the size of a barrel impact maturation?
Water and alcohol impregnate the wood and slowly diffuse out of the barrel sides, to be replaced by ullage. The ullage increases oxidation.
As smaller barrels have a larger surface area to volume ratio, this process is faster compared with larger barrels
What is micro-oxygenation and what are its benefits/risks?
Micro-oxygenation is bubbling oxygen through wine, measured in mg/l per month
It is much more precise than barrel ageing, and saves money over making barrels.
It is an unproven technique however which has risk as longer term outcomes are unknown, and may provide a great chance of spoilage.
Why is wine matured in cellars?
Cellars are cool, which slows down the effect of oxygenation, and prevents some undesirable reactions that can happen at warmer temperatures.
It also reduces evaporation loss
How does an oak barrel’s impact on wine change over time?
Oak has extractable compounds, mainly tannins and aroma compounds.
The levels of these in oak typically halve in year 1, and by year 4 will not contribute noticeably.
Permeability to oxygen and evaporation remain unchanged over time.
What are common barrel sizes for maturation?
Barriques 225l
Foudres - large vessel +2,000l
What types of oak are there and what are their key characteristics for wine maturation?
European - higher in tannin
American - high in lactone (coconut)
Hungarian - tight grain, slow release of compounds
Russian
Slavonian
How does oak type impact cost?
Manufacturing American barrels is about half the cost of European as wood can be sawn, not split.
What are the key processes in making a new barrel?
Season the wood for 2-3 years
Saw/split into staves.
Heat to bend (toasting)