Crude Oil Refining – Part 2 Flashcards
The typical gasoline composition percentage of hydrocarbons (% volume) is as follows:
4-8% alkanes;
2-5% alkenes;
25-40% isoalkanes;
3-7% cycloalkanes;
1-4% cycloalkenes;
and 20-50% total aromatics (0.5-2.5% benzene).
It defined as the percentage by volume of iso-octane in a mixture of iso-octane and n-heptane that knocks with some intensity as the
fuel is being tested.
research octane number (RON)
conversion of heavy naphtha to aromatic and iso-paraffin which have high RON.
Catalytic reforming
light straight paraffins transform to branched chain to increase RON.
Catalytic Isometrization
Upgrade heavy low-value streams to higher value products.
Cracking
high temperatures (typically in the range of 450°C to 750°C)
and pressures (up to about 70 atmospheres) are used to break the large hydrocarbons into smaller ones.
thermal cracking,
mild thermal cracking
Visbreaking
There are two types of visbreakers:
- coil visbreaking (furnace)
- soak visbreaking (soak drum)
is a type of thermal cracking in which the heat required to complete the coking reactions is supplied by a furnace,
Delayed coking
Moderate thermal cracking. Produces petcoke
Coking
is the heart of the refinery and is
where heavy low-value petroleum stream such as vacuum gas oil (VGO) is upgraded into higher value products,
fluidized catalytic cracking (FCC)