Covalent bonding Flashcards
Covalent bonding
attraction between two nuclei and the shared pair of electrons between them
Dative Covalent bonds
Where one atom donates two electrons to an atom or ion to form a bond
Bond Enthalpy
the shorter the bond the higher the bond enthalpy
Bond length
There is a balance between two forces
How are bond length and strength related ?
The greater the electron density between the atoms the stronger attractive force - means that atoms are put in further towards each other - leads to a shorter bond and higher bond enthalpy
Lone pair of electrons
there are atoms with outer shells that contain pairs of electrons which are not involved in the bonding between atoms in the molecule
Electron-pair repulsion theory
the shape of a molecule or ion is determined by the number of electrons pairs in the outer shell surrounding the central atom
Lone pairs
ammonia and water contain non bonding pairs is electrons as well as bonding pairs
Linear
Number of areas: 2
Bond angle: 180
Example: BeCI2
Trigonal Planar
Number of areas: 3
Bond angle: 120
Example: BF3
Tetrahedral
Number of areas: 4
Bond angle: 109.5
Example: CH4
Trigonal Pyramidal
Number of areas: 4 ( 3 bonds + 1 lone pair )
Bond angle: 107
Example: NH3
Non linear
Number of areas: 4 ( 2 bonds + 2 lone pairs )
Bond angle: 104.5
Example: H20
Trigbipy
Number of areas: 5
Bond angle: 90, 120 + 180
Example:
Octahedral
Number of areas: 6
Bond angle: 90 + 180
Example: SF6