corrosion Flashcards
definition of corrosion
destructive chemical reaction between metal and its environment
the main full reaction of corrosion of iron and its two oxidation reactions
2Fe O2 2H2O—>2Fe(oh)2
anodic
Fe—> Fe2+ 4e-
cathodic
02 2h20 4e- —–>4 OH-
what is created in - regions of immunity
- regions of corrosion
- passivity
regions of immunity- no corrosion
corrosion- Fe2+
passivity Fe2O3 formed
7 types of corrosion
uniform pitting crevice intergranular galvanic dealloying environmental
requirements of corrosion?
electrical circuit
moisture (for cathodic reaction )
oxidising agent (for cathodic reaction)
avaliable metal (anode)
process of formation of passive layer?
Iron reacts to form Iron ions, which react with hydroxide ions to form Fe(OH)2 which then react with oxygen to form Fe2O3.
what is the average passive rate and active rates of corrosion
passive 1.116 um/year active 1.116-116 um/year i think
main carbonation of concrete reaction?
2Ca(OH)2 CO2—–>CaCO3+H2O
is the carbonation level in the concrete gradual or abrupt?
abrupt ge, like bang bang abrupt. from PH13 to PH 9 just like that
How many times is the iron oxides volume than the irons and what does this cause
7x causes expansion of reinforcement , cracking, spalling, delamination.
some basic corrosion prevention methods?
membranes, high performance concrete, coating on steel, non corrsive metals, chemical corrsoion inhibitors, (fly ash good for resistivity)
Main factors affecting corrosion rate?
oxygen availability
resistivity of concrete
chloride concentration