corrosion Flashcards

1
Q

definition of corrosion

A

destructive chemical reaction between metal and its environment

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2
Q

the main full reaction of corrosion of iron and its two oxidation reactions

A

2Fe O2 2H2O—>2Fe(oh)2

anodic
Fe—> Fe2+ 4e-
cathodic
02 2h20 4e- —–>4 OH-

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3
Q

what is created in - regions of immunity

  • regions of corrosion
  • passivity
A

regions of immunity- no corrosion
corrosion- Fe2+
passivity Fe2O3 formed

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4
Q

7 types of corrosion

A
uniform
pitting
crevice
intergranular
galvanic
dealloying
environmental
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5
Q

requirements of corrosion?

A

electrical circuit
moisture (for cathodic reaction )
oxidising agent (for cathodic reaction)
avaliable metal (anode)

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6
Q

process of formation of passive layer?

A

Iron reacts to form Iron ions, which react with hydroxide ions to form Fe(OH)2 which then react with oxygen to form Fe2O3.

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7
Q

what is the average passive rate and active rates of corrosion

A

passive 1.116 um/year active 1.116-116 um/year i think

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8
Q

main carbonation of concrete reaction?

A

2Ca(OH)2 CO2—–>CaCO3+H2O

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9
Q

is the carbonation level in the concrete gradual or abrupt?

A

abrupt ge, like bang bang abrupt. from PH13 to PH 9 just like that

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10
Q

How many times is the iron oxides volume than the irons and what does this cause

A

7x causes expansion of reinforcement , cracking, spalling, delamination.

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11
Q

some basic corrosion prevention methods?

A

membranes, high performance concrete, coating on steel, non corrsive metals, chemical corrsoion inhibitors, (fly ash good for resistivity)

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12
Q

Main factors affecting corrosion rate?

A

oxygen availability
resistivity of concrete
chloride concentration

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