Corrosion - 1 Flashcards

1
Q

Corrosion can be generally defined as degradation of a metal by ,,,,,,,,, or ,,,,,,,,, means

A

chemical or electromechanical

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2
Q

Two mechanisms are involved in corrosion, firstly ,,,,, and secondly ,,,,,,,,.

A

An electrical circuit & Chemical reaction.

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3
Q

In a corrosion circuit the current is always ,,,,,

A

direct current (DC).

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4
Q

It is conventionally thought that a current passes from ,,,,,, to ,,,,,,, but electrons are flowing the opposite direction, ,,,,,,

A
  • positive + to negative
    (anode to cathode)
    -from cathode to anode
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5
Q

For a corrosion circuit to exist three things are needed

A
  • Anode
  • Cathode
  • Electrolyte
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6
Q

An anode is a ,,,,,, charged area which becomes positively charged because the atoms ,,,,,, two electrons each

A

positively
release

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7
Q

Anode:
In its ,,,,,, state, the iron atom has 26 of each, protons and electrons

A

passive

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8
Q

Anode:
when the two ,,,,,, are released, the atom still has its 26 ,,,,,,, but only ,,,,,,, . In this state the atom is now ,,,,,

A

electrons
protons
24 electrons
an ion

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9
Q

Anode:
overall positively charged iron by two units and written as ,,,

A

Fe++

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10
Q

An ,,,,,, is a charged particle and can be
positive or negative, a single or a group of atoms, known as a molecule

A

ion

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11
Q

Anode:
This losing of electrons can be shown as: ,,,,,,,.
The Fe++ is called ,,,,,,

A

-Fe → Fe++ + 2e
a positive iron ion

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12
Q

Anode:
An ,,,,, can be positive or negative and is a
,,,,,,,, an atom or a group of atoms

A

ion
charged particle

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13
Q

Anode:
A passive iron atom Fe has ,,,,proton & ,,,,,electrons

A

26
26

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14
Q

Anode:
An iron ion Fe++, has ,,,,,, protons and ,,,,,, electrons

A

26
24

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15
Q

Cathode:
A cathode is ,,,,,, charged area

A

negatively

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16
Q

Cathode:
A cathode is a negatively charged area where there are ,,,,, electrons than needed in its ,,,,,,,.

A

more
passive state

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17
Q

Cathode:
At the cathode the electrons enter into the ,,,,,, to pass back to the ,,,,,

A

electrolyte
anode.

18
Q

Electrolyte:
An electrolyte is a substance, which will ,,,,,,,and ,,,,,,,

A

conduct a current and be broken down by it, (dissociate into ions).

19
Q

,,,,,, is the most abundant electrolyte and
also very efficient

A

Water

20
Q

,,,,,,,, and ,,,,,, in solution are also very efficient
electrolytes.

A

Acids, alkalis and salts

21
Q

As the electrons pass into the electrolyte it is ,,,,,,, into positive and negative ions, as shown by the formula:,,,,,,,,,,, Simultaneously the electrons couple back with the ,,,,,,, ions to form ,,,,,,,, atoms, which join together ,,,,,, to form hydrogen
gas. This is called being ,,,,,, or ,,,,,,,

A

dissociated
-2H2O→2H+ + 2OĦ
hydrogen
two full hydrogen
diatomically
evolved
given off from the cathode

22
Q

Electrolyte:
The hydroxyl ions return to the ,,,,, through the electrolyte carrying the ,,,,,,,

A

anode
electrons.

23
Q

The chemical reaction:
In corrosion, chemical reaction, the formation of corrosion products, only occurs at the ,,,,,,

A

anode

24
Q

If a structure can be made to be the ,,,,, in a circuit, it will not corrode

A

cathode

25
Q

The chemical reaction:
The corrosion triangle shows the three elements needed for corrosion to occur are ,,,,,,

A

anode, cathode and electrolyte.

26
Q

The chemical reaction:
The one most commonly eliminated element is
the ,,,,

A

electrolyte

27
Q

The chemical reaction:
If ,,,,,, is not in direct contact with anode and cathode, there can be no circuit and so no corrosion.

A

electrolyte

28
Q

The chemical reaction:
factors can increase the reaction rate, listed below are some of these are; ,,,,,

A

Temperature
Hygroscopic salts
Aerobic conditions
SRBs or MEM
Bi-metallic contact

29
Q

The chemical reaction:
,,,,,,,and ,,,,,, are the two most common salts,

A

Sulphates
Chlorides

30
Q

The chemical reaction:
chlorides predominant in ,,,,, environments

A

marine

31
Q

The chemical reaction:
sulphates predominant in ,,,, and ,,,,.area

A

industrial
sometimes agricultural

32
Q

The chemical reaction:
By introducing oxygen into the cathodic reaction the number of ,,,,, doubles

A

hydroxyl ions

33
Q

The chemical reaction:
A ,,,,, metal is one, which will not corrode

A

noble

34
Q

The chemical reaction:
The degree of activity can be expressed as ,,,,,

A

potential, in volts

35
Q

The chemical reaction:
The list can be called a ,,,,, list

A

galvanic

36
Q

The chemical reaction:
when the free potentials of the metals are ,,,,, it can also be called the ,,,,, or ,,,,,,,

A

known
electromotive forces series or
electrochemical series

37
Q

The chemical reaction:
Mill scale is formed during the ,,,, operation of steel sections eg RSC, RSA, RSJ

A

rolling

38
Q

The chemical reaction:
The oxides of iron form very quickly at temperatures in ,,,,

A

excess of 580oC

39
Q

The chemical reaction:
During rolling operation, The first oxide formed is ,,,, the next is ,,,,,, and last of all ,,,,

A

iron oxide (FeO), wustite,
Fe3O4, magnetite
Fe2O3, haematite

40
Q

The chemical reaction:
These oxides are compressed during the rolling operation to produce ,,,,,

A

blue mill scale

41
Q

The chemical reaction:
The thickness of mill scale varies from ,,,,

A

25-100um.

42
Q

The chemical reaction:
When mill scale has been removed by any surface preparation method, it can ,,,,,,

A

never recur