Coordination Chemistry Flashcards
This type of associativemechanism where no intermediate is formed and the rate does depends on the nature of the entering group.
Associative interchange mechanism
Bonding-making is more important than bond-breaking.
The dissociative mechanism where no intermediate is formed and the rate does not depends on the nature of the entering group.
Dissociative interchange mechanism
Bonding-breaking is more important than bond-making.
Idenfity the mechanism below.
Dissociative mechanism
The rate depends on breaking the bond of the leaving group.
Idenfity the mechanism below.
Associative mechanism
The rate depends on the properties of the entering group and the encounter complex (intermediate)
As the size of the leaving group increases, the rate of a associative mechanism ________.
Increases, Decreases, or No effect
No effect
As the size of the entering group increases, the rate of an associative mechanism ________.
Increases, Decreases, or No effect
- *Decreases
- (Associative mechanisms are sensitive to the entering group and larger ligands tend to form unfavorable steric interactions with bound ligands)***
As the size of the entering group increases, the rate of a dissociative mechanism ________.
Increases, Decreases, or No effect
No effect
(The rate determining step in a dissociative mechanism is breaking the metal-ligand bond)
As the size of the metal increases, the rate of an associative mechanism ________.
Increases, Decreases, or No effect
Increases
(Large Coordination sphere favors associative mechanism )
As the size of the metal increases, the rate of a dissociative mechanism ________.
Increases, Decreases, or No effect
Increases
As the charge increases on the entering group, the rate of an associative mechanism ________.
Increases, Decreases, or No effect
Increases
As the charge increases on the entering group, the rate of a dissociative mechanism ________.
Increases, Decreases, or No effect
No effect
(The rate determining step in a dissociative mechanism is breaking the metal-ligand bond)
As the negative charge increases on the leaving group, the rate of an associative mechanism ________.
Increases, Decreases, or No effect
Decreases
As the neagtive charge increases on the leaving group, the rate of a dissociative mechanism ________.
Increases, Decreases, or No effect
Decreases
As the charge increases on the metal center, the rate of an associative mechanism ________.
Increases, Decreases, or No effect
Increases
As the charge increases on the metal center, the rate of a dissociative mechanism ________.
Increases, Decreases, or No effect
Decreases