Controlling The Position Of Equilibrium Flashcards
What does a catalyst do to the equilibrium position
It doesn’t affect the equilibrium position, however it increases the rate at which equilibrium is established
Does changing the concentration, pressure or adding catalysts change the value of Kc/Kp
No it doesn’t
What is the only factor that affects the equilibrium constant(K)
Temperature
What effects does an increase in temperature have on the equilibrium constant in an endothermic reaction (the opposite applies to exothermic reactions )
The equilibrium constant increases as temperature rises and equilibrium moves to the right , giving a higher yield of products
the formula for Kc of a reaction with equation: aA+bB= cC+dD
kc= [C]^c[D]^d/[A]^a[B]^b
or basically products/reactants
if Kc=1, it means
the position of equilibrium is halfway between the reactants and the products and that the concentration of the reactants is equal to that of the products
if Kc is bigger than 1, it means
the equilibrium position is to the right and [products]>[reactants]
if Kc< 1, it means
the equilibrium position is to the left of the equation
the larger the value of Kc, the ………………. the equilibrium position lies
further to the right
homogeneous equilibrium
an equilibrium where all species are in the same physical state
heterogeneous equilibrium
it contains species in at least two different states
in Kc expressions for heterogeneous equilibriums, we only include species in which states?
aqueous and gaseous
the formula for the mole fraction of a species
(there are two alternatives )
number of moles of the species/ total number of moles
or
volume of the species/ total volume of gas mixture
the total mole fraction equals?
1
the formula for calculating the total pressure
sum of the partial pressures